Deciphering ligand controlled structural evolution of prussian blue analogues and their electrochemical activation during alkaline water oxidation

B Singh, P Mannu, YC Huang, R Prakash… - Angewandte …, 2022 - Wiley Online Library
Herein, we have demonstrated the control over the structure of precatalysts to tune the
properties of the active catalysts and their water oxidation activity. The reaction of K3 [Fe …

Synthesis, characterization, and in vitro antibacterial and cytotoxic study of Co (II), Ni (II), Cu (II), and Zn (II) complexes of N-(4-methoxybenzyl) N-(phenylethyl) …

A Singh, LB Prasad, K Shiv, R Kumar… - Journal of Molecular …, 2023 - Elsevier
Four new homoleptic complexes of Co (II)[C-1], Ni (II)[C-2], Cu (II)[C-3], and Zn (II)[C-4]
derived from N-(4-methoxybenzyl) N-(phenylethyl) dithiocarbamate ligand (KL) with general …

The supramolecular frameworks and electrocatalytic properties of two new structurally diverse tertiary phosphane-appended nickel (II) and copper (I) thiosquarates

D Srivastava, A Kushwaha, G Kociok-Köhn… - …, 2023 - pubs.rsc.org
In this study, two new heteroleptic complexes with compositions [Ni (mtsq) 1.85 Cl0. 15
(dppe)](CH2Cl2) 0.06 (CH3OH) 0.09 (Ni-mtsq) and [Cu (mtsq)(PPh3) 2](Cu-mtsq)(dppe= 1 …

Designing a Phenalenyl-Based Dinuclear Ni (II) Complex: An Electrocatalyst with Two Single Ni Sites for the Oxygen Evolution Reaction (OER)

N Kamboj, RK Metre - Inorganic Chemistry, 2024 - ACS Publications
A new dinuclear Ni (II) complex 1,[Ni2II (dtbh-PLY) 2], is synthesized from 9-(2-(3, 6-di-tert-
butyl-2-hydroxybenzylidene) hydrazineyl)-1 H-phenalen-1-one, dtbh-PLYH2 ligand, and …

The rigidity and chelation effect of ligands on the hydrogen evolution reaction catalyzed by Ni (ii) complexes

A Mishra, GK Mishra, N Singh, R Kant, K Kumar - Dalton Transactions, 2024 - pubs.rsc.org
With increasing interest in nickel-based electrocatalysts, three heteroleptic Ni (II) dithiolate
complexes with the general formula [Ni (II) L (L′) 2](1–3), L= 2-(methylene-1, 1′-dithiolato) …

Synthesis, crystal structure and screening for anticonvulsant and antianxiety activities of three new Ni (II), Cu (II), and Zn (II) dithiocarbamate complexes

A Singh, R Kumar, K Shiv, SK Pandey… - Journal of Molecular …, 2024 - Elsevier
Abstract A potassium N-(4-fluorobenzyl) N-(naphthalen-1-ylmethyl) dithiocarbamate ligand
(fbnm) has been isolated in a basic medium and its Ni (II), Cu (II), and Zn (II) complexes 1–3 …

Antiproliferative activity of Fe (II), Co (II), Ni (II), Cu (II), and Zn (II) complexes of dithiocarbamate: synthesis, structural characterization, and thermal studies

A Singh, K Shiv, R Singh, MK Bharty, PP Manna… - Dalton …, 2024 - pubs.rsc.org
Five new metal complexes of Fe (II)(1), Co (II)(2), Ni (II)(3), Cu (II)(4), and Zn (II)(5), derived
from an N-cyclohexyl N-(3, 4-dimethoxybenzyl) dithiocarbamate ligand, have been …

Insights into the supramolecular and molecular electrocatalytic properties of 1, 2-bis (diphenylphosphine) ethane appended nickel (ii) 1, 2-dithiosquarate for oxygen …

A Kushwaha, D Srivastava, G Kociok-Köhn… - New Journal of …, 2024 - pubs.rsc.org
A new heteroleptic Ni (II) dithiolate [Nidppe (dtsq)](Nidtsq)(dppe= 1, 2-bis-
(diphenylphosphino) ethane, dtsq2−= 3, 4-dioxocyclobut-1-ene-1, 2-dithiolate) has been …

Dithiocarbamate-based novel anti-histaminic agents: synthesis, characterization, crystal structure and thermal study

A Singh, R Kumar, R Patel, RN Gautam… - Dalton …, 2024 - pubs.rsc.org
A new N-(4-fluorobenzyl) N-(pyridin-2-ylmethyl) dithiocarbamate ligand (fbpm) having
structural similarity to clinically approved antihistaminic drugs (viz. pheniramine …

Ruthenium Azobis (benzothiazole): Electronic Structure and Impact of Substituents on the Electrocatalytic Single-Site Water Oxidation Process

A Singh, B Singh, S Dey, A Indra, GK Lahiri - Inorganic Chemistry, 2023 - ACS Publications
The present article deals with the structurally and spectroelectrochemically characterized
newer class of ruthenium-azoheteroarenes [RuII (Ph-trpy)(Cl)(L)] ClO4,[1] ClO4–[3] ClO4 (Ph …