The fundamental chemistry of which transition element has been most rapidly and
extensively advanced in the last decade? Such a question can provoke a number of …

A great deal of the chemistry of metal thiolates involves thiolate as a bridging ligand.
Thiolates can bridge between two or three metals, to give dinuclear, linear or three …

Publisher Summary This chapter presents a discussion on the bioinorganic chemistry of
pterin-containing molybdenum and tungsten enzymes. The chapter focuses on the current …

H, mida o-aminobenzenethiol 1, 4, 7-triazacyclononane,(NH (CH2 CH2)) 3 2, 2'-bipyridyl,(C,
H, N), tris-pyrazoborate ion, BH (C3 H3N2); butyl, C4H9 dibenzyl trisulphide, Cs H5 CH2 …

A new oxo transfer reaction system of relevance to the molybdenum oxotransferase group of
enzymes has been developed. A set of ligands and their sterically hindered Movi02 …

A series of dioxo-Mo (VI) Schiff base complexes of the type MoOz (RL)(solv) has been
prepared: L= 2-(salicylideneamino)-phenolate (2-)(sap) or 2-(salicylideneamino) …

The oxygen (oxo) atom transfer hypothesis for the enzymatic oxidation/reduction of
generalized substrate X/XO by the molybdenum oxotransferases (hydroxylases) has been …

New molybdenum (VI)-dioxo complexes with a number of ligands having sterically bulky
substituents have been synthesized. One-electron coulometric reduction of Mo02LH2 …

Abstract A series of N2O2 tetradentate ligands with a range of substituents attached to the
nitrogen atoms have been prepared (H2Ln)(n= 1–9). Treatment of these ligands and the …

As possible models for the coordinationof molybdenum by an unsaturated thiolate-thioether
ligand in the mo-lybdenum-pterin cofactor of molybdenum enzymes, Mo02 (dttd), MoOCl …