Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023‏ - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Near-infrared metal agents assisting precision medicine: from strategic design to bioimaging and therapeutic applications

C Li, Y Pang, Y Xu, M Lu, L Tu, Q Li… - Chemical Society …, 2023‏ - pubs.rsc.org
Metal agents have made incredible strides in preclinical research and clinical applications in
recent years, but their short emission/absorption wavelengths continue to be a barrier to …

Luminescent and photofunctional transition metal complexes: From molecular design to diagnostic and therapeutic applications

LCC Lee, KKW Lo - Journal of the American Chemical Society, 2022‏ - ACS Publications
There has been emerging interest in the exploitation of the photophysical and
photochemical properties of transition metal complexes for diagnostic and therapeutic …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021‏ - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Manganese(i) complexes with metal-to-ligand charge transfer luminescence and photoreactivity

P Herr, C Kerzig, CB Larsen, D Häussinger… - Nature Chemistry, 2021‏ - nature.com
Precious metal complexes with the d 6 valence electron configuration often exhibit
luminescent metal-to-ligand charge transfer (MLCT) excited states, which form the basis for …

Janus-type emission from a cyclometalated iron(iii) complex

J Steube, A Kruse, OS Bokareva, T Reuter… - Nature Chemistry, 2023‏ - nature.com
Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …

Charge-transfer processes in metal complexes enable luminescence and memory functions

VWW Yam, AKW Chan, EYH Hong - Nature Reviews Chemistry, 2020‏ - nature.com
Molecular transition-metal–ligand complexes are emerging as useful paradigms in materials
science. Transition metal complexes have diverse metal d electron configurations, oxidation …

Efficient near-infrared luminescence of self-assembled platinum (II) complexes: from fundamentals to applications

YC Wei, KH Kuo, Y Chi, PT Chou - Accounts of Chemical …, 2023‏ - ACS Publications
Conspectus Designing bright and efficient near-infrared (NIR) emitters has drawn much
attention due to numerous applications ranging from biological imaging, medical therapy …

Stable Molybdenum (0) carbonyl complex for upconversion and photoredox catalysis

WR Kitzmann, MS Bertrams, P Boden… - Journal of the …, 2023‏ - ACS Publications
Photoactive complexes with earth-abundant metals have attracted increasing interest in the
recent years fueled by the promise of sustainable photochemistry. However, sophisticated …

Charge‐transfer and spin‐flip states: Thriving as complements

WR Kitzmann, K Heinze - Angewandte Chemie International …, 2023‏ - Wiley Online Library
Transition metal complexes with photoactive charge‐transfer excited states are pervasive
throughout the literature. In particular,[Ru (bpy) 3] 2+(bpy= 2, 2′‐bipyridine), with its metal …