Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Noble-metal nanocrystals with controlled shapes for catalytic and electrocatalytic applications

Y Shi, Z Lyu, M Zhao, R Chen, QN Nguyen… - Chemical …, 2020 - ACS Publications
The successful synthesis of noble-metal nanocrystals with controlled shapes offers many
opportunities to not only maneuver their physicochemical properties but also optimize their …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Surface-plasmon-driven hot electron photochemistry

Y Zhang, S He, W Guo, Y Hu, J Huang… - Chemical …, 2017 - ACS Publications
Visible-light-driven photochemistry has continued to attract heightened interest due to its
capacity to efficiently harvest solar energy and its potential to solve the global energy crisis …

Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures

P Christopher, H **n, S Linic - Nature chemistry, 2011 - nature.com
Catalysis plays a critical role in chemical conversion, energy production and pollution
mitigation. High activation barriers associated with rate-limiting elementary steps require …

Colloidal synthesis of metal nanocrystals: from asymmetrical growth to symmetry breaking

QN Nguyen, C Wang, Y Shang, A Janssen… - Chemical …, 2022 - ACS Publications
Nanocrystals offer a unique platform for tailoring the physicochemical properties of solid
materials to enhance their performances in various applications. While most work on …

Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts

JC Matsubu, S Zhang, L DeRita, NS Marinkovic… - Nature …, 2017 - nature.com
The optimization of supported metal catalysts predominantly focuses on engineering the
metal site, for which physical insights based on extensive theoretical and experimental …

Single‐atom catalysts: a sustainable pathway for the advanced catalytic applications

B Singh, V Sharma, RP Gaikwad, P Fornasiero… - Small, 2021 - Wiley Online Library
A heterogeneous catalyst is a backbone of modern sustainable green industries; and
understanding the relationship between its structure and properties is the key for its …

Isolated Metal Active Site Concentration and Stability Control Catalytic CO2 Reduction Selectivity

JC Matsubu, VN Yang… - Journal of the American …, 2015 - ACS Publications
CO2 reduction by H2 on heterogeneous catalysts is an important class of reactions that has
been studied for decades. However, atomic scale details of structure–function relationships …

Singular characteristics and unique chemical bond activation mechanisms of photocatalytic reactions on plasmonic nanostructures

P Christopher, H **n, A Marimuthu, S Linic - Nature materials, 2012 - nature.com
The field of heterogeneous photocatalysis has almost exclusively focused on semiconductor
photocatalysts. Herein, we show that plasmonic metallic nanostructures represent a new …