Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …
Noble-metal nanocrystals with controlled shapes for catalytic and electrocatalytic applications
The successful synthesis of noble-metal nanocrystals with controlled shapes offers many
opportunities to not only maneuver their physicochemical properties but also optimize their …
opportunities to not only maneuver their physicochemical properties but also optimize their …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Surface-plasmon-driven hot electron photochemistry
Visible-light-driven photochemistry has continued to attract heightened interest due to its
capacity to efficiently harvest solar energy and its potential to solve the global energy crisis …
capacity to efficiently harvest solar energy and its potential to solve the global energy crisis …
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures
Catalysis plays a critical role in chemical conversion, energy production and pollution
mitigation. High activation barriers associated with rate-limiting elementary steps require …
mitigation. High activation barriers associated with rate-limiting elementary steps require …
Colloidal synthesis of metal nanocrystals: from asymmetrical growth to symmetry breaking
Nanocrystals offer a unique platform for tailoring the physicochemical properties of solid
materials to enhance their performances in various applications. While most work on …
materials to enhance their performances in various applications. While most work on …
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts
The optimization of supported metal catalysts predominantly focuses on engineering the
metal site, for which physical insights based on extensive theoretical and experimental …
metal site, for which physical insights based on extensive theoretical and experimental …
Single‐atom catalysts: a sustainable pathway for the advanced catalytic applications
A heterogeneous catalyst is a backbone of modern sustainable green industries; and
understanding the relationship between its structure and properties is the key for its …
understanding the relationship between its structure and properties is the key for its …
Isolated Metal Active Site Concentration and Stability Control Catalytic CO2 Reduction Selectivity
JC Matsubu, VN Yang… - Journal of the American …, 2015 - ACS Publications
CO2 reduction by H2 on heterogeneous catalysts is an important class of reactions that has
been studied for decades. However, atomic scale details of structure–function relationships …
been studied for decades. However, atomic scale details of structure–function relationships …
Singular characteristics and unique chemical bond activation mechanisms of photocatalytic reactions on plasmonic nanostructures
The field of heterogeneous photocatalysis has almost exclusively focused on semiconductor
photocatalysts. Herein, we show that plasmonic metallic nanostructures represent a new …
photocatalysts. Herein, we show that plasmonic metallic nanostructures represent a new …