Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …

In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

Carbide complexes remain a rare class of molecules. Their paucity does not reflect
exceptional instability but is rather due to the generally narrow scope of synthetic …

This study provides atomistic insights into the interface between a single-site catalyst and a
transition metal chalcogenide support and reveals that peak catalytic activity occurs when …

Pre-equilibrium reaction kinetics enable the overall rate of a catalytic reaction to be orders of
magnitude faster than the rate-determining step. Herein, we demonstrate how pre …

Enzymes can activate otherwise unreactive substrates by using residues precisely located in
the active sites. We herein report on a Ga porphyrin which bears a second-sphere sulfonic …

Acidified water electrolysis with fast kinetics is widely regarded as a promising option for
producing H2. The main challenge of this technique is the difficulty in realizing sustainable …

Based on that hydrogen energy is widely used in fuel cells, we focus our interests on the
design and research of new complexes that catalyze the reaction in both directions, such as …

This study uncovers the interconnected reactivity of the three catalytically active sites of an
atomically precise nanocluster Cr3 (py) 3Co6Se8L6 (1 (py) 3, L= Ph2PNTol–, Ph= phenyl …