The Huisgen reaction: milestones of the 1, 3‐dipolar cycloaddition
M Breugst, HU Reissig - Angewandte Chemie International …, 2020 - Wiley Online Library
Abstract The concept of 1, 3‐dipolar cycloadditions was presented by Rolf Huisgen 60 years
ago. Previously unknown reactive intermediates, for example azomethine ylides, were …
ago. Previously unknown reactive intermediates, for example azomethine ylides, were …
C–C bond cleavages of cyclopropenes: operating for selective ring-opening reactions
R Vicente - Chemical Reviews, 2020 - ACS Publications
This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …
Carbonyl–olefin metathesis
H Albright, AJ Davis, JL Gomez-Lopez… - Chemical …, 2021 - ACS Publications
This Review describes the development of strategies for carbonyl–olefin metathesis
reactions relying on stepwise, stoichiometric, or catalytic approaches. A comprehensive …
reactions relying on stepwise, stoichiometric, or catalytic approaches. A comprehensive …
Carbonyl cross-metathesis via deoxygenative gem-di-metal catalysis
Carbonyls and alkenes are versatile functional groups, whose reactivities are cornerstones
of organic synthesis. The selective combination of two carbonyls to form an alkene—a …
of organic synthesis. The selective combination of two carbonyls to form an alkene—a …
Carbonyl Olefin Metathesis and Dehydrogenative Cyclization of Aromatic Ketones and gem‐Difluoroalkenes
Y Zhang, J Wang, Y Guo, S Liu… - Angewandte Chemie …, 2024 - Wiley Online Library
The beauty of one‐pot cascade reaction lies in the efficient disconnection and construction
of several bonds in a single reaction flask, without the isolation of any intermediates. Herein …
of several bonds in a single reaction flask, without the isolation of any intermediates. Herein …
Iron(III)-catalysed carbonyl–olefin metathesis
JR Ludwig, PM Zimmerman, JB Gianino, CS Schindler - Nature, 2016 - nature.com
The olefin metathesis reaction of two unsaturated substrates is one of the most powerful
carbon–carbon-bond-forming reactions in organic chemistry. Specifically, the catalytic olefin …
carbon–carbon-bond-forming reactions in organic chemistry. Specifically, the catalytic olefin …
Catalytic isofunctional reactions—expanding the repertoire of shuttle and metathesis reactions
Transfer hydrogenation, alkene metathesis, and alkyne metathesis possess great value to
the synthetic chemistry community. One of the key features of these processes is their …
the synthetic chemistry community. One of the key features of these processes is their …
Polycyclic aromatic hydrocarbons via iron (iii)-catalyzed carbonyl–olefin metathesis
CC McAtee, PS Riehl, CS Schindler - Journal of the American …, 2017 - ACS Publications
Polycyclic aromatic hydrocarbons are important structural motifs in organic chemistry,
pharmaceutical chemistry, and materials science. The development of a new synthetic …
pharmaceutical chemistry, and materials science. The development of a new synthetic …
Beyond olefins: new metathesis directions for synthesis
MR Becker, RB Watson, CS Schindler - Chemical Society Reviews, 2018 - pubs.rsc.org
The olefin–olefin metathesis reaction has emerged as one of the most important carbon–
carbon bond-forming reactions, as illustrated by its wide use in the synthesis of complex …
carbon bond-forming reactions, as illustrated by its wide use in the synthesis of complex …
Synthesis of 2 H-chromenes: recent advances and perspectives
SL Zheng, L Chen - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
As one type of chromene, 2H-chromenes represent important oxygen heterocycles, which
not only widely exist in natural products, pharmaceutical agents and biologically relevant …
not only widely exist in natural products, pharmaceutical agents and biologically relevant …