Spin crossover in discrete polynuclear iron (II) complexes

RW Hogue, S Singh, S Brooker - Chemical Society Reviews, 2018 - pubs.rsc.org
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials

E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

54 K Spin Transition Temperature Shift in a Fe6L4 Octahedral Cage Induced by Optimal Fitted Multiple Guests

F Yin, J Yang, LP Zhou, X Meng, CB Tian… - Journal of the …, 2024 - ACS Publications
Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

A Magneto‐optical Molecular Device: Interplay of Spin Crossover, Luminescence, Photomagnetism, and Photochromism

M Estrader, J Salinas Uber, LA Barrios… - Angewandte Chemie …, 2017 - Wiley Online Library
A bis (pyrazolylpyridyl) ligand, L, containing a central photochromic dithienylethene spacer
predictably forms a ferrous [Fe2L3] 4+ helicate exhibiting spin crossover (SCO). In solution …

A Charge-Neutral Self-Assembled L2Zn2 Helicate as Bench-Stable Receptor for Anion Recognition at Nanomolar Concentration

D Van Craen, MG Kalarikkal… - Journal of the American …, 2022 - ACS Publications
The field of anion recognition chemistry is dominated by two fundamental approaches to
design receptors. One relies on the formation of covalent bonds resulting in organic and …

Unravelling of a [High Spin—Low Spin]↔[Low Spin—High Spin] Equilibrium in Spin‐Crossover Iron (II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopy

DY Aleshin, R Diego, LA Barrios… - Angewandte …, 2022 - Wiley Online Library
Spin‐crossover between high‐spin (HS) and low‐spin (LS) states of selected transition
metal ions in polynuclear and polymeric compounds is behind their use as multistep …

Iron (II) mediated supramolecular architectures with schiff bases and their spin-crossover properties

D Tesfaye, W Linert, M Gebrezgiabher, Y Bayeh… - Molecules, 2023 - mdpi.com
Supramolecular architectures, which are formed through the combination of inorganic metal
cations and organic ligands by self-assembly, are one of the techniques in modern chemical …

Subcomponent Exchange Transforms an FeII4L4 Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System

AJ McConnell, CM Aitchison, AB Grommet… - Journal of the …, 2017 - ACS Publications
Subcomponent exchange transformed new high-spin FeII4L4 cage 1 into previously-
reported low-spin FeII4L4 cage 2: 2-formyl-6-methylpyridine was ejected in favor of the less …