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Harnessing alcohols as sustainable reagents for late-stage functionalisation: synthesis of drugs and bio-inspired compounds
Alcohol is ubiquitous with unparalleled structural diversity and thus has wide applications as
a native functional group in organic synthesis. It is highly prevalent among biomolecules and …
a native functional group in organic synthesis. It is highly prevalent among biomolecules and …
Advancements in Ni and Co-based catalysts for sustainable syngas production via Bi-reforming of methane: A review of recent advances
In the past decade, Ni and Co-based catalysts have gained significant attention due to their
remarkable efficiency in methanereforming processes. In the case of bireforming of methane …
remarkable efficiency in methanereforming processes. In the case of bireforming of methane …
Iridium-catalyzed enantioconvergent borrowing hydrogen annulation of racemic 1, 4-diols with amines
Y Liu, H Diao, G Hong, J Edward, T Zhang… - Journal of the …, 2023 - ACS Publications
We present an enantioconvergent access to chiral N-heterocycles directly from simple
racemic diols and primary amines, through a highly economical borrowing hydrogen …
racemic diols and primary amines, through a highly economical borrowing hydrogen …
Recent advances in the synthesis of N-heteroarenes via catalytic dehydrogenation of N-heterocycles
Bio-active molecules having N-heteroarene core are widely used for numerous medicinal
applications and as lifesaving drugs. In this direction, dehydrogenation of partially saturated …
applications and as lifesaving drugs. In this direction, dehydrogenation of partially saturated …
Recent advances on non-precious metal-catalyzed C–H functionalization of N-heteroarenes
N-Heteroarenes are widely used for numerous medicinal applications, lifesaving drugs and
show utmost importance as intermediates in chemical synthesis. This feature article …
show utmost importance as intermediates in chemical synthesis. This feature article …
Nickel-catalyzed alkylation of oxindoles with secondary alcohols
Herein, we have demonstrated a simple nickel-catalyzed C-3-selective alkylation of 2-
oxindoles using a wide variety of secondary alkyl alcohols. As a special highlight …
oxindoles using a wide variety of secondary alkyl alcohols. As a special highlight …
Ruthenium-catalyzed divergent deaminative and denitrative C–N cleavages: facile access to quinoxalines
S Liu, J Liang, P Zhang, Z Li, LY Jiao, W Jia… - Organic Chemistry …, 2023 - pubs.rsc.org
Divergent deaminative and denitrative C–N cleavages and cascade transformations using
amines and nitroalkanes have been developed under a highly effective and environmentally …
amines and nitroalkanes have been developed under a highly effective and environmentally …
Iodine-mediated electrochemical C (sp 3)–H cyclization: the synthesis of quinazolinone-fused N-heterocycles
Y Zhang, Z Zhou, Z Li, K Hu, Z Zha… - Chemical …, 2022 - pubs.rsc.org
An efficient iodine-mediated electrochemical C (sp3)–H cyclization was developed under
mild conditions. A variety of functionalized quinazolinone-fused N-heterocycles can be …
mild conditions. A variety of functionalized quinazolinone-fused N-heterocycles can be …
Nitrogen-doped carbon supported nanocobalt for the synthesis of functionalized triazines via oxidative cleavage of biomass derived vicinal diols as carbon synthons
XY Zhang, H Liu, X Sheng, X Mai, S Hou, B Li… - Journal of …, 2022 - Elsevier
The efficient conversion of renewable biomass resources into value-added nitrogen-
containing chemicals has become the focus of recent research. Herein, we report the …
containing chemicals has become the focus of recent research. Herein, we report the …
Chemodivergent coupling of azoarenes with benzyl alcohols via a borrowing hydrogen strategy using a well-defined nickel catalyst
Chemodivergent (de) hydrogenative coupling of azoarenes with benzyl alcohols is achieved
via the NN bond activation using an inexpensive and well-defined (6-OH-bpy) NiCl2 …
via the NN bond activation using an inexpensive and well-defined (6-OH-bpy) NiCl2 …