Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

This study presents a novel method for the regioselective coupling of gem-difluorinated
cyclopropanes with gem-diborylmethane, utilizing a Pd-catalyst system. This innovative …

Boration reaction is a hot topic in the research field of organic synthesis. Undoubtedly, the
diboron reagents, which are stable and easily available starting materials, are widely used …

We report a transition-metal-free coupling of aldehydes and ketones with geminal bis
(boron) building blocks which provides the coupled, homologated carbonyl compound upon …

Stereospecific Csp3 Suzuki–Miyaura cross-coupling could transform stereochemically
complex small molecule synthesis into a simple and broadly accessible process. However …

A preliminary mechanistic approach to the Cu-catalyzed carboboration of alkynes using B2
(pin) 2 was used as a blueprint for the rational design and development of a regiocontrolled …

A Pd-catalyzed decarboxylative cross-coupling of α, β-unsaturated carboxylic acids with
cyclic and acyclic epoxides has been developed. Both β-monosubstituted and β …

A novel, versatile and modular route to unsymmetrical diborane (4) derivatives bearing
either two different diol moieties or one diol and one diamine moiety is presented. Utilising …

The particular nature of boron compounds allows an ample modularity of their properties
ranging from Lewis acids, C‐nucleophiles, B‐nucleophiles, or even conjunctive reagents for …