The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

A guide to direct mechanocatalysis

S Hwang, S Grätz, L Borchardt - Chemical Communications, 2022 - pubs.rsc.org
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …

Mechanochemistry: a force of synthesis

JL Do, T Friščić - ACS central science, 2017 - ACS Publications
The past decade has seen a reawakening of solid-state approaches to chemical synthesis,
driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, ie …

In situ, time-resolved, and mechanistic studies of metal–organic framework nucleation and growth

MJ Van Vleet, T Weng, X Li, JR Schmidt - Chemical reviews, 2018 - ACS Publications
The vast chemical and structural diversity of metal–organic frameworks (MOFs) opens up the
exciting possibility of “crystal engineering” MOFs tailored for particular catalytic or separation …

Mechanochemistry and organic synthesis: from mystical to practical

J Andersen, J Mack - Green chemistry, 2018 - pubs.rsc.org
Perhaps due in no small part to its historical mystique, mechanochemistry has been
shrowded in relative obscurity for quite some time. The successes of mechanochemistry in …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Mechanochemistry of gaseous reactants

C Bolm, JG Hernández - Angewandte Chemie International …, 2019 - Wiley Online Library
In recent years, the application of mechanical energy to chemical systems has repeatedly
proven beneficial to facilitate chemical transformations in various areas in chemistry. Today …

Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent

D Crawford, J Casaban, R Haydon, N Giri… - Chemical …, 2015 - pubs.rsc.org
Grinding solid reagents under solvent-free or low-solvent conditions (mechanochemistry) is
emerging as a general synthetic technique which is an alternative to conventional solvent …

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

S Lukin, LS Germann, T Friščić… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …

Mechanochemistry for organic chemists: an update

D Tan, T Friščić - European Journal of Organic Chemistry, 2018 - Wiley Online Library
We provide a brief overview of recent advances in the use of mechanochemical techniques
for the synthesis of organic molecules and materials, highlighting selected examples of …