Current status and perspectives in oxidative, non-oxidative and CO 2-mediated dehydrogenation of propane and isobutane over metal oxide catalysts

T Otroshchenko, G Jiang, VA Kondratenko… - Chemical Society …, 2021 - pubs.rsc.org
Conversion of propane or butanes from natural/shale gas into propene or butenes, which
are indispensable for the synthesis of commodity chemicals, is an important environmentally …

Dehydrogenation of light alkanes to mono-olefins

C Li, G Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
In the past several decades, light alkane dehydrogenation to mono-olefins, especially
propane dehydrogenation to propylene has gained widespread attention and much …

The tailored role of “defect” sites on γ-alumina: A key to yield an efficient methane dry reforming catalyst with superior nickel utilization

Y Zhang, Y Zu, D He, J Liang, L Zhu, Y Mei… - Applied Catalysis B …, 2022 - Elsevier
Strong metal support interaction between Ni and γ-Al 2 O 3, resulted from the excessive
hydroxyl groups on the Al 2 O 3 support, has restricted Ni utilization in the traditional Ni/Al 2 …

Single Co Sites in Ordered SiO2 Channels for Boosting Nonoxidative Propane Dehydrogenation

W Wang, Y Wu, T Liu, Y Zhao, Y Qu, R Yang… - ACS …, 2022 - ACS Publications
Searching for low-cost, environmentally friendly, and highly active catalysts for C–H bond
activation in propane dehydrogenation (PDH) reaction remains a great challenge. Herein …

Insights into the Nature of Selective Nickel Sites on Ni/Al2O3 Catalysts for Propane Dehydrogenation

R Ma, J Gao, J Kou, DP Dean, CJ Breckner… - ACS …, 2022 - ACS Publications
Nickel has been considered a promising nonprecious metal for propane dehydrogenation
(PDH) because of its appealing ability to activate alkane molecules; however, synthesis of …

Propane Dehydrogenation on Ga2O3-Based Catalysts: Contrasting Performance with Coordination Environment and Acidity of Surface Sites

P Castro-Fernández, D Mance, C Liu, IB Moroz… - ACS …, 2021 - ACS Publications
α-Ga2O3, β-Ga2O3, and γ-Ga2O3 as well as the silica-supported catalysts γ-Ga2O3/SiO2, β-
Ga2O3/SiO2, and Ga (NO3) 3-derived Ga/SiO2 were prepared, characterized, and …

Understanding the Role of Coordinatively Unsaturated Al3+ Sites on Nanoshaped Al2O3 for Creating Uniform Ni–Cu Alloys for Selective Hydrogenation of …

Y Song, S Weng, F Xue, AJ McCue, L Zheng, Y He… - ACS …, 2023 - ACS Publications
In this work, we report a synthesis approach for catalyst preparation using shape-controlled
Al2O3 supports with enriched quantities of coordinatively unsaturated Al3+ centers. These …

Understanding the mechanism of propane dehydrogenation over coordinatively unsaturated Co-O acid-base pairs and the inhibition effect of trace oxygen

Q Shi, Y Song, D Li, Y Wang, Z **e, X Fan, L Kong… - Journal of …, 2024 - Elsevier
High temperature and a reducing atmosphere are characteristic of propane
dehydrogenation (PDH) reaction. Under such condition, the real surface structure of …

Structure–activity relationships in Lewis acid–base heterogeneous catalysis

M Abdelgaid, G Mpourmpakis - ACS Catalysis, 2022 - ACS Publications
Heterogeneous catalysts are the key components in industrial chemical transformations.
Metal oxides are particularly appealing as catalysts owing to their inherent Lewis acid–base …

Highly-Dispersed Zinc Species on Zeolites for the Continuous and Selective Dehydrogenation of Ethane with CO2 as a Soft Oxidant

J Liu, N He, Z Zhang, J Yang, X Jiang, Z Zhang… - ACS …, 2021 - ACS Publications
We report herein the preparation, characterization, and catalytic performance of a series of
heterogeneous catalysts featuring highly dispersed zinc sites on zeolitic SSZ-13 and ZSM-5 …