Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

The synthesis, characterization, and photophysical properties of 4-and 6-coordinate Bi3+
coordination complexes are reported. Bi (bzq) 3 (1) and [Bi (bzq) 2] Br (2)(bzq= benzo [h] …

The rapid expansion of photoredox catalysis and artificial photosynthesis has garnered
renewed interest in the field of photochemistry. While porphyrins have been widely utilized …

As a consequence of global population growth, our modern civilization is facing many
upcoming challenges such as gradually depleting energy resources, anthropogenic climate …

The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …

Metalloporphyrin complexes of the period six metals gold, mercury, thallium, lead and
bismuth are often overlooked in favour of their lighter congeners. These complexes exhibit …

An efficient metalation procedure for bismuth complexes with meso-substituted corrole
ligands is presented. Reaction of 5, 10, 15-tris-pentafluorophenylcorrole H3 (TpFPC) with Bi …

Main-group p-block metals are ideally suited for mediating two-electron reactions because
they cycle between M n and M n+ 2 redox states, as the one-electron state is …