Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques

W Zuo, M Luo, X Liu, J Wu, H Liu, J Li… - Energy & …, 2020 - pubs.rsc.org
Due to their high specific capacities beyond 250 mA hg− 1, lithium-rich oxides have been
considered as promising cathodes for the next generation power batteries, bridging the …

Review of recent development of in situ/operando characterization techniques for lithium battery research

D Liu, Z Shadike, R Lin, K Qian, H Li, K Li… - Advanced …, 2019 - Wiley Online Library
The increasing demands of energy storage require the significant improvement of current Li‐
ion battery electrode materials and the development of advanced electrode materials. Thus …

Origin and regulation of oxygen redox instability in high-voltage battery cathodes

X Liu, GL Xu, VSC Kolluru, C Zhao, Q Li, X Zhou, Y Liu… - Nature Energy, 2022 - nature.com
Oxygen redox at high voltage has emerged as a transformative paradigm for high-energy
battery cathodes such as layered transition-metal oxides by offering extra capacity beyond …

High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes

H Dong, O Tutusaus, Y Liang, Y Zhang… - Nature Energy, 2020 - nature.com
Magnesium batteries have long been pursued as potentially low-cost, high-energy and safe
alternatives to Li-ion batteries. However, Mg2+ interacts strongly with electrolyte solutions …

In situ formed partially disordered phases as earth-abundant Mn-rich cathode materials

Z Cai, B Ouyang, HM Hau, T Chen, R Giovine… - Nature Energy, 2024 - nature.com
Earth-abundant cathode materials are urgently needed to enable scaling of the Li-ion
industry to multiply terawatt hours of annual production, necessitating reconsideration of …

Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes

D Eum, B Kim, SJ Kim, H Park, J Wu, SP Cho, G Yoon… - Nature Materials, 2020 - nature.com
Despite the high energy density of lithium-rich layered-oxide electrodes, their real-world
implementation in batteries is hindered by the substantial voltage decay on cycling. This …

Unlocking anionic redox activity in O3-type sodium 3d layered oxides via Li substitution

Q Wang, S Mariyappan, G Rousse, AV Morozov… - Nature materials, 2021 - nature.com
Sodium ion batteries, because of their sustainability attributes, could be an attractive
alternative to Li-ion technology for specific applications. However, it remains challenging to …

Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

WE Gent, K Lim, Y Liang, Q Li, T Barnes, SJ Ahn… - Nature …, 2017 - nature.com
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at
high potentials, thereby promising high energy densities for lithium-ion batteries. However …

Synchrotron X-ray analytical techniques for studying materials electrochemistry in rechargeable batteries

F Lin, Y Liu, X Yu, L Cheng, A Singer… - Chemical …, 2017 - ACS Publications
Rechargeable battery technologies have ignited major breakthroughs in contemporary
society, including but not limited to revolutions in transportation, electronics, and grid energy …

High reversibility of lattice oxygen redox quantified by direct bulk probes of both anionic and cationic redox reactions

K Dai, J Wu, Z Zhuo, Q Li, S Sallis, J Mao, G Ai, C Sun… - Joule, 2019 - cell.com
The reversibility and cyclability of anionic redox in battery electrodes hold the key to its
practical employments. Here, through map** of resonant inelastic X-ray scattering …