The photofunctionality of the cobalt–hexacarbene complex [Co (III)(PhB (MeIm) 3) 2]+(PhB
(MeIm) 3= tris (3-methylimidazolin-2-ylidene)(phenyl) borate) has been investigated by time …

Reported herein is the synthesis and characterization of a series of mono-and bis-alkynyl
CoIII (TIM) complexes, where TIM is 2, 3, 9, 10-tetramethyl-1, 4, 8, 11-tetraazacyclotetradeca …

The [2+ 2] cyclcoaddition (CA) and subsequent retroelectrocyclization (RE) reactions are
useful in constructing nonplanar donor–acceptor chromophores that exhibit nonlinear …

Controlling electron transfer (ET) processes in donor–bridge–acceptor (DBA) compounds by
mid-IR excitation can enhance our understanding of the ET dynamics and may find practical …

Reported herein are the synthesis and characterization of the Ru (II)(dppe) 2 (dppe= 1, 2-bis
(diphenylphosphino) ethane) mono-alkynyl compounds containing the highly electron …

A new series of mono‐and bis‐alkynyl CoIII (TIM) complexes (TIM= 2, 3, 9, 10‐tetramethyl‐1,
4, 8, 11‐tetraazacyclotetradeca‐1, 3, 8, 10‐tetraene) is reported herein. The trans‐[Co …

The synthesis and characterization of dissymmetric CoIII‐bis‐alkynyl complexes supported
by cyclam (1, 4, 8, 11‐tetraazacyclotetradecane) are reported. A series of trans‐[Co …

Described herein is the synthesis and characterization of macrocyclic CrIII mono-alkynyl
complexes. By using the meso-form of the tetraazamacrocycle HMC (HMC= 5, 5, 7, 12, 12 …

Macrocyclic Cr III bis-alkynyl complexes have recently been used as a precursor in the
synthesis of mono-alkynyl complexes, which can serve as synthetic intermediates towards …

Reported herein are the syntheses of mono-and bis-C2TPA (HC2TPA= 4-ethynyl-N, N-bis (4-
methoxyphenyl) aniline) complexes of CoIII (cyclam)(cyclam= 1, 4, 8, 11 …