Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Synthesis of polycaprolactone: a review

M Labet, W Thielemans - Chemical society reviews, 2009 - pubs.rsc.org
Polycaprolactone (PCL) is an important polymer due to its mechanical properties, miscibility
with a large range of other polymers and biodegradability. Two main pathways to produce …

Controlled ring-opening polymerization of lactide and glycolide

O Dechy-Cabaret, B Martin-Vaca… - Chemical reviews, 2004 - ACS Publications
Synthetic petrochemical-based polymers have had a tremendous industrial impact since the
1940s. Despite the numerous advantages of these materials, two major drawbacks remain …

Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization

C Jérôme, P Lecomte - Advanced drug delivery reviews, 2008 - Elsevier
Advanced drug delivery systems rely on the availability of biocompatible materials.
Moreover, biodegradability is highly desirable in the design of those systems. Consequently …

Biocompatible initiators for lactide polymerization

RH Platel, LM Hodgson, CK Williams - Polymer Reviews, 2008 - Taylor & Francis
The review summarizes recent developments in the preparation and use of new initiators for
the ring opening polymerization of lactide. The review compares different classes of initiator …

Exploiting multimetallic cooperativity in the ring-opening polymerization of cyclic esters and ethers

U Yolsal, PJ Shaw, PA Lowy, R Chambenahalli… - ACS …, 2024 - ACS Publications
The use of multimetallic complexes is a rapidly advancing route to enhance catalyst
performance in the ring-opening polymerization of cyclic esters and ethers. Multimetallic …

A highly active zinc catalyst for the controlled polymerization of lactide

CK Williams, LE Breyfogle, SK Choi… - Journal of the …, 2003 - ACS Publications
We report the preparation, structural characterization, and detailed lactide polymerization
behavior of a new Zn (II) alkoxide complex,(L1ZnOEt) 2 (L1= 2, 4-di-tert-butyl-6-{[(2 ' …

Dinuclear catalysts for the ring opening polymerization of lactide

AB Kremer, P Mehrkhodavandi - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Poly (lactic acid)(PLA) is by far the most commonly produced biodegradable
polyester. Metal-mediated ring opening polymerization of lactide is the most studied route for …

Redox-controlled polymerization of lactide catalyzed by bis (imino) pyridine iron bis (alkoxide) complexes

AB Biernesser, B Li, JA Byers - Journal of the American Chemical …, 2013 - ACS Publications
Bis (imino) pyridine iron bis (alkoxide) complexes have been synthesized and utilized in the
polymerization of (rac)-lactide. The activities of the catalysts were particularly sensitive to the …

Ring‐opening polymerization of lactide with group 3 metal complexes supported by dianionic alkoxy‐amino‐bisphenolate ligands: combining high activity, productivity …

A Amgoune, CM Thomas, T Roisnel… - … –A European Journal, 2006 - Wiley Online Library
A series of new alkoxy‐amino‐bis (phenols)(H2L 1–6) has been synthesized by Mannich
condensations of substituted phenols, formaldehyde, and amino ethers or diamines. The …