Heteroatom-based diradical (oid) s

A Hinz, J Bresien, F Breher, A Schulz - Chemical Reviews, 2023 - ACS Publications
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

Pyrene-based aggregation-induced emission luminogens and their applications

MM Islam, Z Hu, Q Wang, C Redshaw… - Materials Chemistry …, 2019 - pubs.rsc.org
“Unity is force”–Aesop. It is a common phenomenon that traditional chromophores exhibit
high fluorescence in dilute solutions, yet luminescence is quenched at high concentrations …

Triarylboron‐doped acenethiophenes as organic sonosensitizers for highly efficient sonodynamic therapy with low phototoxicity

K Liu, Z Jiang, F Zhao, W Wang, F Jäkle… - Advanced …, 2022 - Wiley Online Library
The development of efficient organic sonosensitizers is crucial for sonodynamic therapy
(SDT) in the field of cancer treatment. Herein, a new strategy for the development of efficient …

Air‐Stable Organic Radicals: New‐Generation Materials for Flexible Electronics?

L Ji, J Shi, J Wei, T Yu, W Huang - Advanced Materials, 2020 - Wiley Online Library
In the last few years, air‐stable organic radicals and radical polymers have attracted
tremendous attention due to their outstanding performance in flexible electronic devices …

Recent developments in and perspectives on three-coordinate boron materials: a bright future

L Ji, S Griesbeck, TB Marder - Chemical Science, 2017 - pubs.rsc.org
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …

Boron-containing organic diradicaloids: dynamically modulating singlet diradical character by Lewis acid–base coordination

J Guo, Y Yang, C Dou, Y Wang - Journal of the American …, 2021 - ACS Publications
Organic diradicaloids have unique open-shell structures and properties and promising
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …

A Stable Chichibabin Diradicaloid with Near‐Infrared Emission

X Chang, ME Arnold, R Blinder, J Zolg… - Angewandte Chemie …, 2024 - Wiley Online Library
Conjugated molecules with multiple radical centers such as the iconic Chichibabin
diradicaloid hold promise as building blocks in materials for quantum sensing and quantum …

Optically induced charge-transfer in donor-acceptor-substituted p- and m- C2B10H12 carboranes

L Wu, M Holzapfel, A Schmiedel, F Peng… - Nature …, 2024 - nature.com
Abstract Icosahedral carboranes, C2B10H12, have long been considered to be aromatic but
the extent of conjugation between these clusters and their substituents is still being debated …

Dual fluorescence of tetraphenylethylene-substituted pyrenes with aggregation-induced emission characteristics for white-light emission

X Feng, C Qi, HT Feng, Z Zhao, HHY Sung… - Chemical …, 2018 - pubs.rsc.org
This article presents a new strategy to achieve white-light emission from single
tetraphenylethylene-substituted pyrenes (TPE-Pys) with aggregation-induced emission (AIE) …

Electron‐deficient conjugated materials via p–π* conjugation with boron: extending monomers to oligomers, macrocycles, and polymers

X Yin, J Liu, F Jäkle - Chemistry–A European Journal, 2021 - Wiley Online Library
The extension of conjugated organoboranes from monomeric species to oligomers,
macrocycles, and polymers offers access to a plethora of fascinating new materials. The p …