The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

The polarity of a radical intermediate profoundly impacts its reactivity and selectivity. To
quantify this influence and predict its effects, the electrophilicity/nucleophilicity of> 500 …

Bicyclo [2.1. 1] hexanes (BCHs) represent an intriguing class of structurally rigid
hydrocarbons that can serve as the bioisosteres of benzenoids in medicinal chemistry …

Abstract C (sp 3)-rich bicyclic hydrocarbon scaffolds, as exemplified by bicyclo [1.1. 1]
pentanes, play an increasingly high-profile role as saturated bioisosteres of benzenoids in …

In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …

A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

Electrochemical nitrogen reduction reaction (NRR) over nonprecious‐metal and single‐
atom catalysts has received increasing attention as a sustainable strategy to synthesize …

Most photoredox catalysts in current use are precious metal complexes or synthetically
elaborate organic dyes, the cost of which can impede their application for large-scale …