Continuous Flow Upgrading of Selected C2–C6 Platform Chemicals Derived from Biomass

R Gerardy, DP Debecker, J Estager, P Luis… - Chemical …, 2020 - ACS Publications
The ever increasing industrial production of commodity and specialty chemicals inexorably
depletes the finite primary fossil resources available on Earth. The forecast of population …

Continuous flow organic chemistry: successes and pitfalls at the interface with current societal challenges

R Gérardy, N Emmanuel, T Toupy… - European Journal of …, 2018 - Wiley Online Library
This review intends to provide the reader with a clear and concise overview of how
preparative continuous flow organic chemistry could potentially impact on current important …

Heterogeneous catalysts for conversion of biodiesel-waste glycerol into high-added-value chemicals

N Tabassum, R Pothu, A Pattnaik, R Boddula, P Balla… - Catalysts, 2022 - mdpi.com
The valuable products produced from glycerol transformation have become a research route
that attracted considerable benefits owing to their huge volumes in recent decades (as a …

Highly efficient process for the conversion of glycerol to acrylic acid via gas phase catalytic oxidation of an allyl alcohol intermediate

X Li, Y Zhang - ACS Catalysis, 2016 - ACS Publications
The conversion of glycerol, the main byproduct of the biodiesel industry, to acrylic acid is
one of the most attractive biomass to biochemical processes. It represents millions of tons of …

Sustaining the Transition from a petrobased to a Biobased Chemical Industry with Flow Chemistry

R Gérardy, R Morodo, J Estager, P Luis… - Accounts on Sustainable …, 2020 - Springer
In the current context of transitioning to more sustainable chemical processes, the upgrading
of biobased platform molecules (ie, the chemical transformation of widely available low …

Oxidative dehydration of glycerol to acrylic acid over vanadium-substituted cesium salts of Keggin-type heteropolyacids

X Li, Y Zhang - Acs Catalysis, 2016 - ACS Publications
Acrylic acid is one of the most desired products from bioglycerol. In this work, we
demonstrated that Keggin-type heteropoly compounds (HPCs) act as efficient bifunctional …

Influence of the niobium supported species on the catalytic dehydration of glycerol to acrolein

C García-Sancho, JA Cecilia, A Moreno-Ruiz… - Applied Catalysis B …, 2015 - Elsevier
The present work deals with the catalytic performance of a series of supported niobium
oxide (1–12 wt% Nb 2 O 5) catalysts in the gas phase dehydration of glycerol. The niobium …

Highly selective oxidation of ethyl lactate to ethyl pyruvate catalyzed by mesoporous vanadia–titania

W Zhang, G Innocenti, P Oulego, V Gitis, H Wu… - ACS …, 2018 - ACS Publications
The direct oxidative dehydrogenation of lactates with molecular oxygen is a “greener”
alternative for producing pyruvates. Here we report a one-pot synthesis of mesoporous …

Gas-phase dehydration of glycerol to acrolein catalyzed by hybrid acid sites derived from transition metal hydrogen phosphate and meso-HZSM-5

X Ren, F Zhang, M Sudhakar, N Wang, J Dai, L Liu - Catalysis Today, 2019 - Elsevier
The dehydration of glycerol to acrolein is a useful approach for the value-added conversion
of bio-diesel derived glycerol. To improve the acrolein yield, the transition metal hydrogen …

Glycerol adsorption and mechanism of dehydration to acrolein over TiO2 surface: A density functional theory study

Z Babaei, AN Chermahini, M Dinari - Journal of colloid and interface …, 2020 - Elsevier
Glycerol as major by-product of biodiesel production cab be converted to high-value added
materials such as acrolein. The details of this transformation mechanism is obscure using …