Synthetically tuned electronic and geometrical properties of intermetallic compounds as effective heterogeneous catalysts

VS Marakatti, SC Peter - Progress in Solid State Chemistry, 2018 - Elsevier
Intermetallic compounds (IMCs) exhibits unique structural features accompanied by
appropriate changes in the electronic structures. These electronically and geometrically …

Intermetallic compounds: promising inorganic materials for well-structured and electronically modified reaction environments for efficient catalysis

S Furukawa, T Komatsu - Acs Catalysis, 2017 - ACS Publications
An overview of the catalytic properties of intermetallic compounds has been made to provide
a comprehensive understanding regarding (1) what intermetallic catalysts can do,(2) their …

Hydrogenation of citral: a wide-spread model reaction for selective reduction of α, β-unsaturated aldehydes

A Stolle, T Gallert, C Schmöger, B Ondruschka - RSC advances, 2013 - pubs.rsc.org
Citral (1) is an α, β-unsaturated aldehyde classified as a monoterpenoid compound from the
3, 6-dimethyloctane series, characterized by a head-to-tail linkage of two isoprenoid …

Highly efficient and selective hydrogenation of unsaturated carbonyl compounds using Ni–Sn alloy catalysts

S Khairi, T Hara, N Ichikuni, S Shimazu - Catalysis Science & …, 2012 - pubs.rsc.org
Inexpensive Ni–Sn-based alloy catalysts, both bulk and supported, exhibited high selectivity
in the hydrogenation of a wide range of unsaturated carbonyl compounds and produced …

Selective Hydrogenation of α, β-Unsaturated Aldehydes Over Intermetallic Compounds─ A Critical Review

P Adamski, H Zhang, S Kaur, X Chen… - Chemistry of …, 2024 - ACS Publications
The selective hydrogenation of α, β-unsaturated aldehydes is a complex reaction. Of
industrial interest is the thermodynamically unfavored hydrogenation of the carbonyl group …

One-pot selective conversion of C5-furan into 1, 4-pentanediol over bulk Ni–Sn alloy catalysts in an ethanol/H 2 O solvent mixture

MD Astuti, T Hara, N Ichikuni, S Shimazu - Green Chemistry, 2019 - pubs.rsc.org
Inexpensive bulk Ni–Sn alloy-based catalysts demonstrated a unique catalytic property in
the selective conversion of C5-furan compounds (eg, furfuraldehyde (FFald), furfuryl alcohol …

Novel preparation method of bimetallic Ni-In alloy catalysts supported on amorphous alumina for the highly selective hydrogenation of furfural

MD Astuti, DR Mujiyanti, UT Santoso, S Shimazu - Molecular Catalysis, 2018 - Elsevier
A novel preparation method for bimetallic nickel-indium alloy catalysts supported on
amorphous alumina (Ni-In (x)/AA; x= Ni/In molar ratio) catalysts has been developed and …

[PDF][PDF] Selective conversion of 2-methylfuran to 1, 4-pentanediol catalyzed by bimetallic Ni-Sn alloy

R Rodiansono, AM Dewi, S Husain… - Bulletin of Chemical …, 2019 - academia.edu
The selective conversion of 2-methylfuran (2-MeF) to 1, 4-pentanediol (1, 4-PeD) over
bimetallic nickeltin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using …

Intermetallic compounds in catalysis

M Armbrüster - Encyclopedia of catalysis, 2002 - Wiley Online Library
In catalysis, intermetallic compounds play an important role as precursors for skeletal
catalysts or can be formed under reaction conditions and influence the catalytic properties …

A chemical bottom-up and successive top-down approach for nanoporous SnO 2 hollows from Ni 3 Sn 2 nanoalloys: high surface area photocatalysts and anode …

J Choi, SY Han, J **, J Kim, JH Park, SM Lee… - Journal of Materials …, 2013 - pubs.rsc.org
This work shows that a chemical bottom-up and successive top-down approach is a good
synthetic strategy for nanoporous hollow materials. The heating of 3 eq. nickel chloride and …