Predicting binding free energies: frontiers and benchmarks

DL Mobley, MK Gilson - Annual review of biophysics, 2017 - annualreviews.org
Binding free energy calculations based on molecular simulations provide predicted affinities
for biomolecular complexes. These calculations begin with a detailed description of a …

Overview of the SAMPL5 host–guest challenge: Are we doing better?

J Yin, NM Henriksen, DR Slochower, MR Shirts… - Journal of computer …, 2017 - Springer
The ability to computationally predict protein-small molecule binding affinities with high
accuracy would accelerate drug discovery and reduce its cost by eliminating rounds of trial …

Assessment of binding affinity via alchemical free-energy calculations

M Kuhn, S Firth-Clark, P Tosco, ASJS Mey… - Journal of Chemical …, 2020 - ACS Publications
Free-energy calculations have seen increased usage in structure-based drug design.
Despite the rising interest, automation of the complex calculations and subsequent analysis …

Approaches for calculating solvation free energies and enthalpies demonstrated with an update of the FreeSolv database

G Duarte Ramos Matos, DY Kyu… - Journal of Chemical & …, 2017 - ACS Publications
Solvation free energies can now be calculated precisely from molecular simulations,
providing a valuable test of the energy functions underlying these simulations. Here we …

Overview of the SAMPL6 host–guest binding affinity prediction challenge

A Rizzi, S Murkli, JN McNeill, W Yao, M Sullivan… - Journal of computer …, 2018 - Springer
Accurately predicting the binding affinities of small organic molecules to biological
macromolecules can greatly accelerate drug discovery by reducing the number of …

Automated adaptive absolute binding free energy calculations

F Clark, GR Robb, DJ Cole, J Michel - Journal of Chemical Theory …, 2024 - ACS Publications
Alchemical absolute binding free energy (ABFE) calculations have substantial potential in
drug discovery, but are often prohibitively computationally expensive. To unlock their …

Blind prediction of cyclohexane–water distribution coefficients from the SAMPL5 challenge

CC Bannan, KH Burley, M Chiu, MR Shirts… - Journal of computer …, 2016 - Springer
In the recent SAMPL5 challenge, participants submitted predictions for cyclohexane/water
distribution coefficients for a set of 53 small molecules. Distribution coefficients (log D) …

Comparison of receptor–ligand restraint schemes for alchemical absolute binding free energy calculations

F Clark, G Robb, DJ Cole, J Michel - Journal of Chemical Theory …, 2023 - ACS Publications
Alchemical absolute binding free energy calculations are of increasing interest in drug
discovery. These calculations require restraints between the receptor and ligand to restrict …

Hydrophobe challenge: A joint experimental and computational study on the host–guest binding of hydrocarbons to cucurbiturils, allowing explicit evaluation of guest …

KI Assaf, M Florea, J Antony… - The Journal of …, 2017 - ACS Publications
The host–guest complexation of hydrocarbons (22 guest molecules) with cucurbit [7] uril was
investigated in aqueous solution using the indicator displacement strategy. The binding …

The role of water in host-guest interaction

V Rizzi, L Bonati, N Ansari, M Parrinello - Nature Communications, 2021 - nature.com
One of the main applications of atomistic computer simulations is the calculation of ligand
binding free energies. The accuracy of these calculations depends on the force field quality …