Surface oxygen atom as a cooperative ligand in Pd nanoparticle catalysis for selective hydration of nitriles to amides in water: experimental and theoretical studies
On the basis of an insight in surface science that Pd surfaces partially covered with oxygen
adatoms (Oad) show higher reactivity for water dissociation than clean Pd surfaces, we …
adatoms (Oad) show higher reactivity for water dissociation than clean Pd surfaces, we …
Surface oxygen-assisted Pd nanoparticle catalysis for selective oxidation of silanes to silanols.
Just add O (2): Based on the fact that an oxygen-adsorbed Pd metal surface shows higher
reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles …
reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles …
Catalytic Synthesis of Silanols by Hydroxylation of Hydrosilanes: From Chemoselectivity to Enantioselectivity
WS Huang, H Xu, H Yang, LW Xu - Chemistry–A European …, 2024 - Wiley Online Library
As a crucial class of functional molecules in organosilicon chemistry, silanols are found
valuable applications in the fields of modern science and will be a potentially powerful …
valuable applications in the fields of modern science and will be a potentially powerful …
Low-temperature hydrogenation of acetaldehyde to ethanol on H-precovered Au (111)
Gold-based classical high surface area catalysts have been widely investigated for
hydrogenation reactions, but fundamental studies on model catalysts are lacking. We …
hydrogenation reactions, but fundamental studies on model catalysts are lacking. We …
The effects of adsorbed water on gold catalysis and surface chemistry
Water has important effects on several reactions occurring over gold catalysts. In this work,
we review studies demonstrating the interactions of water in surface chemistry and catalysis …
we review studies demonstrating the interactions of water in surface chemistry and catalysis …
Recent advances for hydration reaction of nitriles in different catalytic systems
X Yujie, H Dandan, W Wanqing - Chinese Journal of Organic …, 2021 - sioc-journal.cn
Nitriles can be used to construct new carbon-carbon and carbon-hetero bonds which result
in diverse products. Among them, amide groups can be found in a large variety of drugs …
in diverse products. Among them, amide groups can be found in a large variety of drugs …
Hydration of nitriles to amides in water by SiO2-supported Ag catalysts promoted by adsorbed oxygen atoms
A series of silica-supported silver catalysts with similar Ag loading (5 or 7wt%) but with
different preparation methods (calcination in air and reduction by H2 or NaBH4) were …
different preparation methods (calcination in air and reduction by H2 or NaBH4) were …
Structure revealing H/D exchange with co-adsorbed hydrogen and water on gold
A fundamental understanding of the interactions between coadsorbed water and hydrogen
on metallic surfaces is critical to many chemical processes including catalysis and …
on metallic surfaces is critical to many chemical processes including catalysis and …
Water Chemistry beneath Graphene: Condensation of a Dense OH–H2O Phase under Graphene
Room temperature oxygen hydrogenation below graphene flakes supported by Ir (111) is
investigated through a combination of X-ray photoelectron spectroscopy, scanning tunneling …
investigated through a combination of X-ray photoelectron spectroscopy, scanning tunneling …
First-principles study of oxygen coverage effect on hydrogen oxidation on Ni (1 1 1) surface
S Liu, T Ishimoto, M Koyama - Applied Surface Science, 2015 - Elsevier
The anodic oxidation reactions of solid oxide fuel cells are studied by density functional
theory method under different oxygen coverage on the Ni (1 1 1) surface. Co-adsorbed …
theory method under different oxygen coverage on the Ni (1 1 1) surface. Co-adsorbed …