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Environmental speciation of actinides
Although minor in abundance in Earth's crust (U, 2–4 ppm; Th, 10–15 ppm) and in seawater
(U, 0.003 ppm; Th, 0.0007 ppm), light actinides (Th, Pa, U, Np, Pu, Am, and Cm) are …
(U, 0.003 ppm; Th, 0.0007 ppm), light actinides (Th, Pa, U, Np, Pu, Am, and Cm) are …
Mineral–water interface reactions of actinides
Reactions of the light actinide ions (Th to Cm) at the mineral− aqueous solution interface
have attracted much attention during recent years. Initially research was mainly driven by the …
have attracted much attention during recent years. Initially research was mainly driven by the …
Structure and reactivity of the calcite–water interface
The zetapotential of calcite in contact with aqueous solutions of varying composition is
determined for pre-equilibrated suspensions by means of electrophoretic measurements …
determined for pre-equilibrated suspensions by means of electrophoretic measurements …
[HTML][HTML] Sorption speciation of lanthanides/actinides on minerals by TRLFS, EXAFS and DFT studies: a review
X Tan, M Fang, X Wang - Molecules, 2010 - mdpi.com
Lanthanides/actinides sorption speciation on minerals and oxides by means of time
resolved laser fluorescence spectroscopy (TRLFS), extended X-ray absorption fine structure …
resolved laser fluorescence spectroscopy (TRLFS), extended X-ray absorption fine structure …
Reactivity of the calcite–water-interface, from molecular scale processes to geochemical engineering
Surface reactions on calcite play an important role in geochemical and environmental
systems, as well as many areas of industry. In this review, we present investigations of …
systems, as well as many areas of industry. In this review, we present investigations of …
Structure and surface complexation at the calcite (104)–water interface
Calcite is the most stable polymorph of calcium carbonate (CaCO3) under ambient
conditions and is ubiquitous in natural systems. It plays a major role in controlling pH in …
conditions and is ubiquitous in natural systems. It plays a major role in controlling pH in …
Metal-ion partitioning during low-temperature precipitation and dissolution of anhydrous carbonates and sulphates
ME Böttcher, M Dietzel - 2011 - pubs.geoscienceworld.org
Anhydrous carbonate and sulphate-bearing solids are formed on Earth under very different
environmental conditions and are the most abundant constituents in so-called chemical …
environmental conditions and are the most abundant constituents in so-called chemical …
Microbial effects on mineral–radionuclide interactions and radionuclide solid-phase capture processes
Understanding the environmental and biogeochemical behaviour of radionuclides is
essential for managing our nuclear legacy safely. Remediation efforts and the concept of …
essential for managing our nuclear legacy safely. Remediation efforts and the concept of …
[HTML][HTML] U (VI) behaviour in hyperalkaline calcite systems
KF Smith, ND Bryan, AN Swinburne, P Bots… - … et Cosmochimica Acta, 2015 - Elsevier
The behaviour of U (VI) in hyperalkaline fluid/calcite systems was studied over a range of U
(VI) concentrations (5.27× 10− 5 μM to 42.0 μM) and in two high pH systems, young and old …
(VI) concentrations (5.27× 10− 5 μM to 42.0 μM) and in two high pH systems, young and old …
Competitive reaction of neptunium (V) and uranium (VI) in potassium–sodium carbonate-rich aqueous media: speciation study with a focus on high-resolution X-ray …
Neptunium (V) and uranium (VI) are precipitated from an aqueous potassium–sodium-
containing carbonate-rich solution, and the solid phases are investigated. U/Np M4, 5-edge …
containing carbonate-rich solution, and the solid phases are investigated. U/Np M4, 5-edge …