Environmental speciation of actinides

K Maher, JR Bargar, GE Brown Jr - Inorganic chemistry, 2013 - ACS Publications
Although minor in abundance in Earth's crust (U, 2–4 ppm; Th, 10–15 ppm) and in seawater
(U, 0.003 ppm; Th, 0.0007 ppm), light actinides (Th, Pa, U, Np, Pu, Am, and Cm) are …

Mineral–water interface reactions of actinides

H Geckeis, J Lützenkirchen, R Polly, T Rabung… - Chemical …, 2013 - ACS Publications
Reactions of the light actinide ions (Th to Cm) at the mineral− aqueous solution interface
have attracted much attention during recent years. Initially research was mainly driven by the …

Structure and reactivity of the calcite–water interface

F Heberling, TP Trainor, J Lützenkirchen, P Eng… - Journal of colloid and …, 2011 - Elsevier
The zetapotential of calcite in contact with aqueous solutions of varying composition is
determined for pre-equilibrated suspensions by means of electrophoretic measurements …

[HTML][HTML] Sorption speciation of lanthanides/actinides on minerals by TRLFS, EXAFS and DFT studies: a review

X Tan, M Fang, X Wang - Molecules, 2010 - mdpi.com
Lanthanides/actinides sorption speciation on minerals and oxides by means of time
resolved laser fluorescence spectroscopy (TRLFS), extended X-ray absorption fine structure …

Reactivity of the calcite–water-interface, from molecular scale processes to geochemical engineering

F Heberling, D Bosbach, JD Eckhardt, U Fischer… - Applied …, 2014 - Elsevier
Surface reactions on calcite play an important role in geochemical and environmental
systems, as well as many areas of industry. In this review, we present investigations of …

Structure and surface complexation at the calcite (104)–water interface

F Heberling, T Klačić, P Raiteri, JD Gale… - … science & technology, 2021 - ACS Publications
Calcite is the most stable polymorph of calcium carbonate (CaCO3) under ambient
conditions and is ubiquitous in natural systems. It plays a major role in controlling pH in …

Metal-ion partitioning during low-temperature precipitation and dissolution of anhydrous carbonates and sulphates

ME Böttcher, M Dietzel - 2011 - pubs.geoscienceworld.org
Anhydrous carbonate and sulphate-bearing solids are formed on Earth under very different
environmental conditions and are the most abundant constituents in so-called chemical …

Microbial effects on mineral–radionuclide interactions and radionuclide solid-phase capture processes

DR Brookshaw, RAD Pattrick, JR Lloyd… - Mineralogical …, 2012 - cambridge.org
Understanding the environmental and biogeochemical behaviour of radionuclides is
essential for managing our nuclear legacy safely. Remediation efforts and the concept of …

[HTML][HTML] U (VI) behaviour in hyperalkaline calcite systems

KF Smith, ND Bryan, AN Swinburne, P Bots… - … et Cosmochimica Acta, 2015 - Elsevier
The behaviour of U (VI) in hyperalkaline fluid/calcite systems was studied over a range of U
(VI) concentrations (5.27× 10− 5 μM to 42.0 μM) and in two high pH systems, young and old …

Competitive reaction of neptunium (V) and uranium (VI) in potassium–sodium carbonate-rich aqueous media: speciation study with a focus on high-resolution X-ray …

T Vitova, I Pidchenko, D Schild, T Prüßmann… - Inorganic …, 2019 - ACS Publications
Neptunium (V) and uranium (VI) are precipitated from an aqueous potassium–sodium-
containing carbonate-rich solution, and the solid phases are investigated. U/Np M4, 5-edge …