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Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges
IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
Recent strategies to develop innovative photosensitizers for enhanced photodynamic therapy
TC Pham, VN Nguyen, Y Choi, S Lee, J Yoon - Chemical reviews, 2021 - ACS Publications
This review presents a robust strategy to design photosensitizers (PSs) for various species.
Photodynamic therapy (PDT) is a photochemical-based treatment approach that involves the …
Photodynamic therapy (PDT) is a photochemical-based treatment approach that involves the …
Recent advances in the chemistry and applications of N-heterocyclic carbenes
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications
SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …
species in the cross-coupling cycle. Today, there are methods available to generate the …
N-Heterocyclic carbene complexes in C–H activation reactions
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
Mechanistic aspects of the palladium‐catalyzed Suzuki‐Miyaura cross‐coupling reaction
MC D'Alterio, È Casals‐Cruañas… - … A European Journal, 2021 - Wiley Online Library
The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …
among the most outstanding ones. Herein, a brief historical overview of insights regarding …
N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …
research fields, and it is not possible to imagine modern transition metal and main group …
Homogeneous catalysis by cobalt and manganese pincer complexes
Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …
based on complexes of noble metals. In recent years, tremendous progress has been made …
Applications of palladium-catalyzed C–N cross-coupling reactions
P Ruiz-Castillo, SL Buchwald - Chemical reviews, 2016 - ACS Publications
Pd-catalyzed cross-coupling reactions that form C–N bonds have become useful methods to
synthesize anilines and aniline derivatives, an important class of compounds throughout …
synthesize anilines and aniline derivatives, an important class of compounds throughout …