Hydration reactions catalyzed by transition metal–NHC (NHC= N-heterocyclic carbene) complexes
P Gao, M Szostak - Coordination Chemistry Reviews, 2023 - Elsevier
The catalytic addition of water to unsaturated C–C or C–N π bonds represent one of the
most important and environmentally sustainable methods to form C–O bonds for the …
most important and environmentally sustainable methods to form C–O bonds for the …
Recent advances in pincer–nickel catalyzed reactions
Organometallic catalysts have played a key role in accomplishing numerous synthetically
valuable organic transformations that are either otherwise not possible or inefficient. The use …
valuable organic transformations that are either otherwise not possible or inefficient. The use …
Organoselenium ligands for heterogeneous and nanocatalytic systems: development and applications
Organoselenium ligands have attracted great attention among researchers during the past
two decades. Various homogeneous, heterogeneous and nanocatalytic systems have been …
two decades. Various homogeneous, heterogeneous and nanocatalytic systems have been …
Fe3O4@SiO2@KIT-6@2-ATP@CuI as a catalyst for hydration of benzonitriles and reduction of nitroarenes
In this paper, a new type of magnetic mesoporous material (Fe3O4@ SiO2@ KIT-6@ 2-
ATP@ CuI) was designed and synthesized and its application in the synthesis of amides …
ATP@ CuI) was designed and synthesized and its application in the synthesis of amides …
Cationic ruthenium (II)-CNC pincer complexes as phosphine-free catalysts for nitrile hydration to amides in aqueous medium
We report the synthesis, characterization, and catalytic activity of a series of electron-rich,
phosphine-free complexes featuring multiple N-heterocyclic carbene (NHC) ligands, namely …
phosphine-free complexes featuring multiple N-heterocyclic carbene (NHC) ligands, namely …
A comprehensive analysis of the metal–nitrile bonding in an organo-diiron system
Nitriles (N≡ CR) are ubiquitous in coordination chemistry, yet literature studies on metal–
nitrile bonding based on a multi-technique approach are rare. We selected an easily …
nitrile bonding based on a multi-technique approach are rare. We selected an easily …
Hydrogen bond mediated conversion of benzenenitriles and arylacetonitriles to amides: an “on/in-water” reaction strategy
Owing to the myriad of applications that amides have, hydration of nitriles has emerged as
one of the most preferred atom-efficient synthesis methods. Being kinetically slow, this …
one of the most preferred atom-efficient synthesis methods. Being kinetically slow, this …
Hydration of Aliphatic Nitriles Catalyzed by an Osmium Polyhydride: Evidence for an Alternative Mechanism
JC Babón, MA Esteruelas, AM López… - Inorganic Chemistry, 2021 - ACS Publications
The hexahydride OsH6 (PiPr3) 2 competently catalyzes the hydration of aliphatic nitriles to
amides. The main metal species under the catalytic conditions are the trihydride osmium (IV) …
amides. The main metal species under the catalytic conditions are the trihydride osmium (IV) …
Organoselenium Compounds as an Emerging Class of Stabilizers of applied Nanomaterials for Applications in the Catalysis of Organic Reactions
Nanomaterials have revolutionized various scientific and industrial domains due to their
exceptional properties and diverse applications. Yet, challenges persist in achieving their …
exceptional properties and diverse applications. Yet, challenges persist in achieving their …
Silica supported spinel structured cobalt ferrite multifunctional nanocatalyst for hydration of nitriles and oxidative decarboxylation of phenylacetic acids
S Hazarika, G Borah - Applied Organometallic Chemistry, 2022 - Wiley Online Library
The silica‐supported cobalt ferrite spinel nanocatalyst has been successfully synthesized by
the coprecipitation method and extensively characterized by FTIR, XRD, SEM‐EDX, TEM …
the coprecipitation method and extensively characterized by FTIR, XRD, SEM‐EDX, TEM …