Various catalysts in homogeneous or heterogeneous catalysis deploy unconventional
reaction pathways by lowering the activation energy (AE) barrier, controlling the selectivity …

N-heterocyclic carbene gold (I) chloride and hydroxide complexes are regularly used as
synthons to access various oxygen-, nitrogen-or carbon-bound gold complexes. They are …

N-Heterocyclic carbenes (NHCs) are nowadays ubiquitous in organometallic chemistry and
catalysis. Recently, a synthetic method which makes use of weak bases and desirable …

N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …

N-heterocyclic carbene (NHC) metal complexes have gained an incredible amount of
attention in the course of the last two decades and have become indispensable as an …

Imidazolium salts have found ubiquitous applications as N-heterocyclic carbene precursors
and metal nanoparticle stabilizers in catalysis and metallodrug research. Substituents …

The present study describes a class of “large-but-flexible” Pd-NHC complexes derived from
dibenzobarrelene. These complexes have been successfully employed in Pd-catalyzed …

N-Heterocyclic carbenes (NHCs) have emerged as a privileged ligand family in
organometallic chemistry, widely recognized for their unique steric and electronic properties …

Seven unsymmetrical imidazolium chlorides featuring a mesityl (Mes) or 2, 6-
diisopropylphenyl substituent (Dip) on one of their nitrogen atoms and a cycloalkyl group of …

C-Amino-1, 2, 4-triazoles are challenging polynitrogen substrates for metal-catalyzed
arylation due to their multidentate character, enhanced coordinating ability and decreased …