Heterometallic supramolecular polymers (HMSPs) comprising two or more heterometal ions
have drawn significant research interest in the last two decades because of their attractive …

We report a class of isolable bis‐cyclometallated iridium precatalysts (ImIr) and their use in
regioselective ortho− C− H borylation of aromatic, heteroaromatic, acrylic, and aliphatic …

Herein, we report a metal-free, scalable, and cascade protocol for constructing
polysubstituted pyridines from N, N-dimethyl enaminones and α, β-unsaturated …

Rendering a common ligand scaffold anionic and then pairing it with a chiral cation
represents an alternative strategy for develo** enantioselective versions of challenging …

Systematic analysis of the effect of para‐substituents (H, Cl, Br and OMe) on the meso‐
phenyl group in vanadyl meso‐tetraphenylporphyrins ([VIVO (TPP)](R= H, 1),[VIVO …

Boron compounds are widely employed in organic chemistry, pharmaceuticals, and
materials science. Among them, borylated heterocycles serve as versatile synthons for the …

The benzoxazole and benzothiazole moieties were used as innate directing groups for Pd
(II)-and Ru (II)-catalyzed C–H arylation of the biorelevant heterocycles 2-arylbenzoxazole …

Transition‐metal‐catalyzed selective and efficient activation of an inert C–H bond in an
organic substrate is of importance for the development of streamlined synthetic …

The iridium-catalyzed C–H borylation of benzamides typically leads to meta and para
selectivities using state-of-the-art iridium-based N, N-chelating bipyridine ligands. However …

The iridium-catalyzed CH borylation of benzamides typically leads to and selectivities using
state-of-the-art iridium-based,-chelating bipyridine ligands. However, reaching selectivity …