Ultrafast electron diffraction: Visualizing dynamic states of matter

D Filippetto, P Musumeci, RK Li, BJ Siwick… - Reviews of Modern …, 2022 - APS
Since the discovery of electron-wave duality, electron scattering instrumentation has
developed into a powerful array of techniques for revealing the atomic structure of matter …

Capturing chemistry in action with electrons: realization of atomically resolved reaction dynamics

AA Ischenko, PM Weber, RJD Miller - Chemical reviews, 2017 - ACS Publications
One of the grand challenges in chemistry has been to directly observe atomic motions
during chemical processes. The depiction of the nuclear configurations in space-time to …

Real-time observation of internal motion within ultrafast dissipative optical soliton molecules

K Krupa, K Nithyanandan, U Andral, P Tchofo-Dinda… - Physical review …, 2017 - APS
Real-time access to the internal ultrafast dynamics of complex dissipative optical systems
opens new explorations of pulse-pulse interactions and dynamic patterns. We present the …

Roadmap of ultrafast x-ray atomic and molecular physics

L Young, K Ueda, M Gühr… - Journal of Physics B …, 2018 - iopscience.iop.org
X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high
harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and …

The photochemical ring-opening of 1, 3-cyclohexadiene imaged by ultrafast electron diffraction

TJA Wolf, DM Sanchez, J Yang, RM Parrish… - Nature …, 2019 - nature.com
The ultrafast photoinduced ring-opening of 1, 3-cyclohexadiene constitutes a textbook
example of electrocyclic reactions in organic chemistry and a model for photobiological …

Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction

J Yang, X Zhu, TJA Wolf, Z Li, JPF Nunes, R Coffee… - Science, 2018 - science.org
Conical intersections play a critical role in excited-state dynamics of polyatomic molecules
because they govern the reaction pathways of many nonadiabatic processes. However …

Ultrafast X-ray scattering reveals vibrational coherence following Rydberg excitation

B Stankus, H Yong, N Zotev, JM Ruddock… - Nature …, 2019 - nature.com
The coherence and dephasing of vibrational motions of molecules constitute an integral part
of chemical dynamics, influence material properties and underpin schemes to control …

Self-referenced coherent diffraction x-ray movie of Ångstrom-and femtosecond-scale atomic motion

JM Glownia, A Natan, JP Cryan, R Hartsock, M Kozina… - Physical review …, 2016 - APS
Time-resolved femtosecond x-ray diffraction patterns from laser-excited molecular iodine are
used to create a movie of intramolecular motion with a temporal and spatial resolution of 30 …

Hyperpolarizability and operational magic wavelength in an optical lattice clock

RC Brown, NB Phillips, K Beloy, WF McGrew… - Physical review …, 2017 - APS
Optical clocks benefit from tight atomic confinement enabling extended interrogation times
as well as Doppler-and recoil-free operation. However, these benefits come at the cost of …

Different flavors of nonadiabatic molecular dynamics

F Agostini, BFE Curchod - Wiley interdisciplinary reviews …, 2019 - Wiley Online Library
The Born‐Oppenheimer approximation constitutes a cornerstone of our understanding of
molecules and their reactivity, partly because it introduces a somewhat simplified …