Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

The first highly enantioselective catalytic synthesis of P-stereogenic secondary phosphine-
boranes was realized by the asymmetric addition of primary phosphine to electron-deficient …

The stereoselective synthesis of molecules bearing stereogenic phosphorus (V) centers
represents an enduring challenge in organic chemistry. Although stereospecific nucleophilic …

Since the development of BisP* ligand by Imamoto, P-stereogenic phosphines bearing a
bulky tert-butyl group and a smaller alkyl group have demonstrated extraordinary proficiency …

The practical synthesis of P-stereogenic tertiary phosphines, which have wide applications
in asymmetric catalysis, materials, and pharmaceutical chemistry, represents a significant …

Phosphorus fluoride exchange (PFEx) represents a cutting-edge advancement in catalytic
click-reaction technology. Drawing inspiration from nature's phosphate connectors, PFEx …

P‐stereogenic tert‐and sec‐phosphines have wide applications in asymmetric catalysis,
materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a …

The development of transition-metal-catalyzed methods for the synthesis of P-chiral
phosphine derivatives poses a considerable challenge. Herein, we present a direct Pd/**ao …

The catalytic asymmetric synthesis of P‐chiral phosphorus compounds is an important way
to construct P‐chiral ligands. Herein, we report a new strategy that adopts the pyridinyl …