Hierarchical nanomaterials assembled from peptoids and other sequence-defined synthetic polymers

Z Li, B Cai, W Yang, CL Chen - Chemical Reviews, 2021 - ACS Publications
In nature, the self-assembly of sequence-specific biopolymers into hierarchical structures
plays an essential role in the construction of functional biomaterials. To develop synthetic …

Engineering precise sequence-defined polymers for advanced functions

Q Shi, Z Deng, M Hou, X Hu, S Liu - Progress in Polymer Science, 2023 - Elsevier
Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …

Degradable living plastics programmed by engineered spores

C Tang, L Wang, J Sun, G Chen, J Shen… - Nature Chemical …, 2024 - nature.com
Plastics are widely used materials that pose an ecological challenge because their wastes
are difficult to degrade. Embedding enzymes and biomachinery within polymers could …

Digital micelles of encoded polymeric amphiphiles for direct sequence reading and ex vivo label-free quantification

Q Shi, H Yin, R Song, J Xu, J Tan, X Zhou, J Cen… - Nature Chemistry, 2023 - nature.com
Identification and quantification of synthetic polymers in complex biological milieu are crucial
for delivery, sensing and scaffolding functions, but conventional techniques based on …

Iterative exponential growth of stereo-and sequence-controlled polymers

JC Barnes, DJC Ehrlich, AX Gao, FA Leibfarth… - Nature …, 2015 - nature.com
Chemists have long sought sequence-controlled synthetic polymers that mimic nature's
biopolymers, but a practical synthetic route that enables absolute control over polymer …

Molecular nanoparticles are unique elements for macromolecular science: From “nanoatoms” to giant molecules

WB Zhang, X Yu, CL Wang, HJ Sun, IF Hsieh… - …, 2014 - ACS Publications
In this Perspective, we present a unique approach to the design and synthesis of giant
molecules based on “nanoatoms” for engineering structures across multiple length scales …

A general approach to sequence-controlled polymers using macrocyclic ring opening metathesis polymerization

WR Gutekunst, CJ Hawker - Journal of the American Chemical …, 2015 - ACS Publications
A new and general strategy for the synthesis of sequence-defined polymers is described that
employs relay metathesis to promote the ring opening polymerization of unstrained …

Recent progress in the design of monodisperse, sequence‐defined macromolecules

SC Solleder, RV Schneider, KS Wetzel… - Macromolecular …, 2017 - Wiley Online Library
This review describes different synthetic strategies towards sequence‐defined,
monodisperse macromolecules, which are built up by iterative approaches and lead to …

Preparation of poly (ε-caprolactone)-based tissue engineering scaffolds by stereolithography

L Elomaa, S Teixeira, R Hakala, H Korhonen… - Acta biomaterialia, 2011 - Elsevier
A photocrosslinkable poly (ε-caprolactone)(PCL)-based resin was developed and applied
using stereolithography. No additional solvents were required during the structure …

Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces

B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …