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Hierarchical nanomaterials assembled from peptoids and other sequence-defined synthetic polymers
In nature, the self-assembly of sequence-specific biopolymers into hierarchical structures
plays an essential role in the construction of functional biomaterials. To develop synthetic …
plays an essential role in the construction of functional biomaterials. To develop synthetic …
Engineering precise sequence-defined polymers for advanced functions
Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
Degradable living plastics programmed by engineered spores
C Tang, L Wang, J Sun, G Chen, J Shen… - Nature Chemical …, 2024 - nature.com
Plastics are widely used materials that pose an ecological challenge because their wastes
are difficult to degrade. Embedding enzymes and biomachinery within polymers could …
are difficult to degrade. Embedding enzymes and biomachinery within polymers could …
Digital micelles of encoded polymeric amphiphiles for direct sequence reading and ex vivo label-free quantification
Q Shi, H Yin, R Song, J Xu, J Tan, X Zhou, J Cen… - Nature Chemistry, 2023 - nature.com
Identification and quantification of synthetic polymers in complex biological milieu are crucial
for delivery, sensing and scaffolding functions, but conventional techniques based on …
for delivery, sensing and scaffolding functions, but conventional techniques based on …
Iterative exponential growth of stereo-and sequence-controlled polymers
Chemists have long sought sequence-controlled synthetic polymers that mimic nature's
biopolymers, but a practical synthetic route that enables absolute control over polymer …
biopolymers, but a practical synthetic route that enables absolute control over polymer …
Molecular nanoparticles are unique elements for macromolecular science: From “nanoatoms” to giant molecules
In this Perspective, we present a unique approach to the design and synthesis of giant
molecules based on “nanoatoms” for engineering structures across multiple length scales …
molecules based on “nanoatoms” for engineering structures across multiple length scales …
A general approach to sequence-controlled polymers using macrocyclic ring opening metathesis polymerization
A new and general strategy for the synthesis of sequence-defined polymers is described that
employs relay metathesis to promote the ring opening polymerization of unstrained …
employs relay metathesis to promote the ring opening polymerization of unstrained …
Recent progress in the design of monodisperse, sequence‐defined macromolecules
SC Solleder, RV Schneider, KS Wetzel… - Macromolecular …, 2017 - Wiley Online Library
This review describes different synthetic strategies towards sequence‐defined,
monodisperse macromolecules, which are built up by iterative approaches and lead to …
monodisperse macromolecules, which are built up by iterative approaches and lead to …
Preparation of poly (ε-caprolactone)-based tissue engineering scaffolds by stereolithography
L Elomaa, S Teixeira, R Hakala, H Korhonen… - Acta biomaterialia, 2011 - Elsevier
A photocrosslinkable poly (ε-caprolactone)(PCL)-based resin was developed and applied
using stereolithography. No additional solvents were required during the structure …
using stereolithography. No additional solvents were required during the structure …
Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces
B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …
various applications as well as fundamental studies. Notably, this field of science which can …