While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Virtually all organosulfur compounds react with Fe (0) carbonyls to give the title complexes.
These reactions are reviewed in light of major advances over the past few decades, spurred …

Recently, substantial efforts had been made in the field of synthetic iron compounds as
structural and functional models of the hydrogenase enzyme active site for the purpose of …

The effect of the nature of the dithiolato ligand on the physical and electrochemical
properties of synthetic H-cluster mimics of the [FeFe]-hydrogenase is still of significant …

Eight diiron hexacarbonyl complexes bearing a 1, 8-dithionaphthalenyl bridging linkage as
mimics of the diiron subunit of [FeFe]-hydrogenase are reported. Reaction of Fe3 (CO) 12 …

Eight dithiolato-, diselenolato-, and mixed S, Se-Fe2 (CO) 6 complexes based on peri-
substituted naphthalene and phenanthrene dichalcogenides are prepared by oxidative …

This study focuses on [FeFe]-hydrogenase and its metallorganic mimics in terms of
electronic and photophysical properties, which can be applied to the electrochemical and/or …

Chlorine-substituted benzenedithiols have been coordinated to iron carbonyl to yield a
series of hydrogen-producing electrocatalysts:[Fe2 (μ-S2C6H4–x Cl x)(CO) 6], where x= 0, 2 …

Ar‐BIANH2 bearing different substituents on the aryl rings have been synthesized in high
yield by reduction of the corresponding bis (aryl) acenaphthenequinonediimine (Ar‐BIAN) …

Various transition metal complexes of porphyrins, M-meso-tetrakis-(p-NH 2 phenyl)
porphyrins [where M= Fe, Co, Ni, and Cu] have been synthesized and employed for …