Copper–oxygen complexes revisited: structures, spectroscopy, and reactivity

CE Elwell, NL Gagnon, BD Neisen, D Dhar… - Chemical …, 2017 - ACS Publications
A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …

Copper-catalysed cross-coupling: an untapped potential

S Thapa, B Shrestha, SK Gurung, R Giri - Organic & biomolecular …, 2015 - pubs.rsc.org
Copper is emerging as a viable catalytic metal for cross-coupling reactions to construct
carbon–carbon (C–C) bonds. Recent revelations that Cu-catalysts can execute with high …

[BOOK][B] Kinetics and mechanism of reactions of transition metal complexes

RG Wilkins - 1991 - Wiley Online Library
This thoroughly revised and updated edition of one of the classics of kinetics text books
continues the successful concept of the 1974 edition: In its first part, a simplified approach to …

Copper-catalyzed electrochemical C–H amination of arenes with secondary amines

QL Yang, XY Wang, JY Lu, LP Zhang… - Journal of the …, 2018 - ACS Publications
Electrochemical oxidation represents an environmentally friendly solution to conventional
methods that require caustic stoichiometric chemical oxidants. However, C–H …

The Myth of d8 Copper(III)

IM DiMucci, JT Lukens, S Chatterjee… - Journal of the …, 2019 - ACS Publications
Seventeen Cu complexes with formal oxidation states ranging from CuI to CuIII are
investigated through the use of multiedge X-ray absorption spectroscopy (XAS) and density …

The role of organometallic copper (III) complexes in homogeneous catalysis

A Casitas, X Ribas - Chemical Science, 2013 - pubs.rsc.org
Organometallic CuIII species have been invoked in many copper-catalyzed reactions, but
until recently, experimental evidences were lacking. The advent of new spectroscopic …

Organocopper reagents: substitution, conjugate addition, carbo/metallocupration, and other reactions

BH Lipshutz, S Sengupta - Organic Reactions, 2004 - Wiley Online Library
Well over a decade ago, two reviews were contributed to the Organic Reactions series
covering substitution and conjugate addition reactions in organocopper chemistry. Their …

Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry

CS Mullins, VL Pecoraro - Coordination chemistry reviews, 2008 - Elsevier
Recent advances in the study of the oxygen evolving complex (OEC) of photosystem II (PSII)
include structural information attained from several X-ray crystallographic (XRD) and …

Csp3–Csp3 Bond-Forming Reductive Elimination from Well-Defined Copper(III) Complexes

M Paeth, SB Tyndall, LY Chen, JC Hong… - Journal of the …, 2019 - ACS Publications
Carbon–carbon bond-forming reductive elimination from elusive organocopper (III)
complexes has been considered the key step in many copper-catalyzed and organocuprate …

Well-defined organometallic Copper (III) complexes: Preparation, characterization and reactivity

H Liu, Q Shen - Coordination Chemistry Reviews, 2021 - Elsevier
Organocopper (III) species were generally considered as the key intermediates in a variety
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …