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Nonadiabatic dynamics studied by liquid-jet time-resolved photoelectron spectroscopy
Conspectus The development of the liquid microjet technique by Faubel and co-workers has
enabled the investigation of high vapor pressure liquids and solutions utilizing high-vacuum …
enabled the investigation of high vapor pressure liquids and solutions utilizing high-vacuum …
The photophysics of nucleic acids: Consequences for the emergence of life
Absorption of ultraviolet (UV) radiation can trigger a variety of photophysical and
photochemical reactions in nucleic acids. In the prebiotic era, on the surface of the early …
photochemical reactions in nucleic acids. In the prebiotic era, on the surface of the early …
Excited-state dynamics in the RNA nucleotide uridine 5′-monophosphate investigated using femtosecond broadband transient absorption spectroscopy
Damage to RNA from ultraviolet radiation induces chemical modifications to the
nucleobases. Unraveling the excited states involved in these reactions is essential; …
nucleobases. Unraveling the excited states involved in these reactions is essential; …
Characterizing conical intersections in DNA/RNA Nucleobases with Multiconfigurational wave functions of varying active space size
We characterize the photochemically relevant conical intersections between the lowest-lying
accessible electronic excited states of the different DNA/RNA nucleobases using Cholesky …
accessible electronic excited states of the different DNA/RNA nucleobases using Cholesky …
Detection of the thietane precursor in the UVA formation of the DNA 6-4 photoadduct
Notwithstanding the central biological role of the (6-4) photoadduct in the induction of skin
cancer by sunlight, crucial mechanistic details about its formation have evaded …
cancer by sunlight, crucial mechanistic details about its formation have evaded …
Solvent‐Dependent Stabilization of a Charge Transfer State is the Key to Ultrafast Triplet State Formation in an Epigenetic DNA Nucleoside
Deoxy‐5‐formylcytidine (5fdCyd), a naturally occurring nucleoside found in mammalian
DNA and mitochondrial RNA, exhibits important epigenetic functionality in biological …
DNA and mitochondrial RNA, exhibits important epigenetic functionality in biological …
Solvent effects in the ultraviolet and X-ray absorption spectra of pyridazine in aqueous solution
Electrostatic interaction of the solvent with the solute and fluctuations of the solvent
configurations may make excitation energies of the solute different from those in the gas …
configurations may make excitation energies of the solute different from those in the gas …
Relaxation dynamics of hydrated thymine, thymidine, and thymidine monophosphate probed by liquid jet time-resolved photoelectron spectroscopy
The relaxation dynamics of thymine and its derivatives thymidine and thymidine
monophosphate are studied using time-resolved photoelectron spectroscopy applied to a …
monophosphate are studied using time-resolved photoelectron spectroscopy applied to a …
Excited-state absorption of uracil in the gas phase: Map** the main decay paths by different electronic structure methods
We present a computational study of the one-photon and excited-state absorption (ESA)
from the two lowest energy excited states of uracil in the gas phase: an nπ* dark state (1n) …
from the two lowest energy excited states of uracil in the gas phase: an nπ* dark state (1n) …
On the origin of the photostability of DNA and RNA monomers: Excited state relaxation mechanism of the pyrimidine chromophore
Today's genetic composition is the result of continual refinement processes on primordial
heterocycles present in prebiotic Earth and at least partially regulated by ultraviolet …
heterocycles present in prebiotic Earth and at least partially regulated by ultraviolet …