Catalytic hydrodeoxygenation of bio-oil and model compounds-Choice of catalysts, and mechanisms

ARK Gollakota, CM Shu, PK Sarangi… - … and Sustainable Energy …, 2023 - Elsevier
In recent decades, the quest for renewable and sustainable alternatives, namely
biomass/bio waste, has been prompted by rising environmental concerns, demand, and the …

Controlling heterogeneous catalysis with organic monolayers on metal oxides

AH Jenkins, JW Medlin - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus A key theme of heterogeneous catalysis research is achieving control of the
environment surrounding the active site to precisely steer the reactivity toward desired …

Catalytic hydrodeoxygenation of lignin-derived oxygenates: catalysis, mechanism, and effect of process conditions

VS Prabhudesai, L Gurrala, R Vinu - Energy & Fuels, 2021 - ACS Publications
The high oxygen content of pyrolysis bio-oil with many organic functional groups in it limits
its direct application as a blendstock. The upgradation of biomass-derived oxygenates into …

Encapsulated Ni-Co alloy nanoparticles as efficient catalyst for hydrodeoxygenation of biomass derivatives in water

D Wang, W Gong, J Zhang, M Han, C Chen… - Chinese journal of …, 2021 - Elsevier
Catalytic hydrodeoxygenation (HDO) is one of the most promising strategies to transform
oxygen-rich biomass derivatives into high value-added chemicals and fuels, but highly …

Highly dispersed Pd on zeolite/carbon nanocomposites for selective hydrodeoxygenation of biomass-derived molecules under mild conditions

R Zong, H Li, WT Ding, H Huang - ACS Sustainable Chemistry & …, 2021 - ACS Publications
Herein, a defective zeolite–carbon (CFR@ HZSM-5) nanocomposite-supported nano-scale
Pd catalyst (Pd/CFR@ HZSM-5) was facilely synthesized for selective “H2-free” …

Significant promotion of surface oxygen vacancies on bimetallic CoNi nanocatalysts for hydrodeoxygenation of biomass-derived vanillin to produce …

M Liu, J Zhang, L Zheng, G Fan… - … Sustainable Chemistry & …, 2020 - ACS Publications
Constructing surface defective structures (eg, oxygen vacancies) on metal catalysts may
alter their surface electronic properties, thus controlling the absorption and activation of …

The crucial role of catalyst wettability for hydrogenation of biomass and carbon dioxide over heterogeneous catalysts

M Wei, Y Kuang, Z Duan, H Li - Cell Reports Physical Science, 2023 - cell.com
Wettability regulation is an effective strategy to modulate the active sites of catalysts and
provides a powerful method to create efficient catalysts for a wide range of reactions …

Effect of Surface Hydrophobicity of Pd/Al2O3 on Vanillin Hydrodeoxygenation in a Water/Oil System

P Hao, DK Schwartz, JW Medlin - ACS Catalysis, 2018 - ACS Publications
Pickering emulsions stabilized by solid catalysts have received an increasing amount of
attention as a reaction platform because of potential applications in the chemical industry …

Robust MOF-derived carbon-supported bimetallic Ni–Co catalysts for aqueous phase hydrodeoxygenation of vanillin

Y Zhang, J Zhao, G Fan, L Yang, F Li - Dalton Transactions, 2022 - pubs.rsc.org
Currently, rapidly increasing consumption of fossil resources has propelled the upgrading of
biomass as an alternative and sustainable technology to produce important chemicals and …

Enhancing Activity of Ni2P-Based Catalysts by a Yolk–Shell Structure and Transition Metal-Do** for Catalytic Transfer Hydrogenation of Vanillin

G Li, H Li - Energy & Fuels, 2021 - ACS Publications
Catalytic transfer hydrogenation (CTH) is regarded as a promising technology for upgrading
biomass to fuels and valuable chemicals in the presence of heterogeneous catalysts. In this …