Selective catalytic synthesis of α-alkylated ketones and β-disubstituted ketones via acceptorless dehydrogenative cross-coupling of alcohols
Herein, a phosphine-free pincer ruthenium (III) catalyzed β-alkylation of secondary alcohols
with primary alcohols to α-alkylated ketones and two different secondary alcohols to β …
with primary alcohols to α-alkylated ketones and two different secondary alcohols to β …
Iron-catalyzed α-alkylation of ketones with secondary alcohols: access to β-Disubstituted carbonyl compounds
An iron-catalyzed borrowing hydrogen strategy has been applied in the synthesis of β-
branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have …
branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have …
Blue-light-induced iron-catalyzed α-alkylation of ketones
We report a visible-light-induced iron-catalyzed α-alkylation of ketones. The photocatalytic
system is based on the single diaminocyclopentadienone iron tricarbonyl complex. Two …
system is based on the single diaminocyclopentadienone iron tricarbonyl complex. Two …
Cobalt-catalyzed acceptorless dehydrogenation of alcohols to carboxylate salts and hydrogen
DR Pradhan, S Pattanaik, J Kishore… - Organic letters, 2020 - ACS Publications
The facile oxidation of alcohols to carboxylate salts and H2 is achieved using a simple and
readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an …
readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an …
Ruthenium-catalyzed α-alkylation of ketones using secondary alcohols to β-disubstituted ketones
An assortment of aromatic ketones was successfully functionalized with a variety of
unactivated secondary alcohols that serve as alkylating agents, providing β-disubstituted …
unactivated secondary alcohols that serve as alkylating agents, providing β-disubstituted …
Catalytic formal conjugate addition: direct synthesis of δ-hydroxynitriles from nitriles and allylic alcohols
Alcohols and nitrile functionalities have widespread applications in biochemical and
chemical synthesis. Catalytic transformations involving C–C bond formation relying on …
chemical synthesis. Catalytic transformations involving C–C bond formation relying on …
Direct catalytic symmetrical, unsymmetrical N, N-dialkylation and cyclization of acylhydrazides using alcohols
Herein, direct N, N-dialkylation of acylhydrazides using alcohols is reported. This catalytic
protocol provides one-pot synthesis of both symmetrical and unsymmetrical N, N …
protocol provides one-pot synthesis of both symmetrical and unsymmetrical N, N …
Ruthenium‐Catalyzed Synthesis of α‐Alkylated Ketones and Quinolines in an Aqueous Medium via a Hydrogen‐Borrowing Strategy Using Ketones and Alcohols
Herein, we report a simple, efficient, and sustainable method for the synthesis of α‐alkylated
ketones and quinolines using a hydrogen‐borrowing strategy, which has emerged as a …
ketones and quinolines using a hydrogen‐borrowing strategy, which has emerged as a …
Ruthenium-catalyzed selective hydrogenation of epoxides to secondary alcohols
A ruthenium (II)-catalyzed highly selective Markovnikov hydrogenation of terminal epoxides
to secondary alcohols is reported. Diverse substitutions on the aryl ring of styrene oxides are …
to secondary alcohols is reported. Diverse substitutions on the aryl ring of styrene oxides are …
Manganese (I) catalyzed α-alkenylation of amides using alcohols with liberation of hydrogen and water
BK Pandia, C Gunanathan - The Journal of Organic Chemistry, 2021 - ACS Publications
Herein, unprecedented manganese-catalyzed direct α-alkenylation of amides using
alcohols is reported. Aryl amides are reacted with diverse primary alcohols, which provided …
alcohols is reported. Aryl amides are reacted with diverse primary alcohols, which provided …