Nanochemistry: synthesis in diminishing dimensions

GA Ozin - Advanced materials, 1992 - Wiley Online Library
Atomic and molecular size devices are the ultimate goal of those working on, for example,
nanoscale patterning and templating techniques. The various approaches to nanophase …

Thin-film processing routes for combinatorial materials investigations—a review

PJ McGinn - ACS Combinatorial Science, 2019 - ACS Publications
High-throughput combinatorial investigations are transforming materials discovery, phase
diagram development, and processing optimization. Thin-film deposition techniques are …

Perovskites by design: a toolbox of solid-state reactions

RE Schaak, TE Mallouk - Chemistry of Materials, 2002 - ACS Publications
In recent years, many soft-chemical reactions of layered perovskites have been reported,
and they can be classified into sets of similar reactions. Simple ion-exchange and …

Turning down the heat: design and mechanism in solid-state synthesis

A Stein, SW Keller, TE Mallouk - Science, 1993 - science.org
Solid-state compounds have historically been prepared through high-temperature solid-
solid reactions. New mechanistic understanding of these reactions suggests possible routes …

Chimie douce approaches to the synthesis of metastable oxide materials

J Gopalakrishnan - Chemistry of Materials, 1995 - ACS Publications
While thermodynamically stable metal oxides and other solids could be prepared by
conventional high-temperature (ceramic) methods, syntheses of the more important meta …

Quantifying the regime of thermodynamic control for solid-state reactions during ternary metal oxide synthesis

NJ Szymanski, YW Byeon, Y Sun, Y Zeng, J Bai… - Science …, 2024 - science.org
The success of solid-state synthesis often hinges on the first intermediate phase that forms,
which determines the remaining driving force to produce the desired target material. Recent …

Toward reaction-by-design: achieving kinetic control of solid state chemistry with metathesis

AJ Martinolich, JR Neilson - Chemistry of Materials, 2017 - ACS Publications
The control of solid state reaction pathways will enable the design and discovery of new
functional inorganic materials. A range of synthetic approaches have been used to shift solid …

Topochemical synthesis of three-dimensional perovskites from lamellar precursors

RE Schaak, TE Mallouk - Journal of the American Chemical …, 2000 - ACS Publications
A topochemical route to nondefect, three-dimensional perovskites from lamellar Dion−
Jacobson and Ruddlesden− Popper precursors was demonstrated. The method involves …

Circumventing diffusion in kinetically controlled solid-state metathesis reactions

AJ Martinolich, JA Kurzman… - Journal of the American …, 2016 - ACS Publications
Solid-state diffusion is often the primary limitation in the synthesis of crystalline inorganic
materials and prevents the potential discovery and isolation of new materials that may not be …

Hexanuclear and higher nuclearity clusters of the Groups 4–7 metals with stabilizing π-donor ligands

TG Gray - Coordination Chemistry Reviews, 2003 - Elsevier
The chemistry of early transition element clusters with π-donor ligands is growing rapidly.
We review the syntheses of these compounds, with an emphasis on progress in the last 6 …