Elementary vibrational model for transport properties of dense fluids
SA Khrapak - Physics Reports, 2024 - Elsevier
A vibrational model of transport properties of dense fluids assumes that solid-like oscillations
of atoms around their temporary equilibrium positions dominate the dynamical picture. The …
of atoms around their temporary equilibrium positions dominate the dynamical picture. The …
Simple liquids' quasiuniversality and the hard-sphere paradigm
JC Dyre - Journal of Physics: Condensed Matter, 2016 - iopscience.iop.org
This topical review discusses the quasiuniversality of simple liquids' structure and dynamics
and two possible justifications of it. The traditional one is based on the van der Waals picture …
and two possible justifications of it. The traditional one is based on the van der Waals picture …
Perspective: Excess-entropy scaling
JC Dyre - The Journal of chemical physics, 2018 - pubs.aip.org
This article gives an overview of excess-entropy scaling, the 1977 discovery by Rosenfeld
that entropy determines properties of liquids like viscosity, diffusion constant, and heat …
that entropy determines properties of liquids like viscosity, diffusion constant, and heat …
Modified entropy scaling of the transport properties of the Lennard-Jones fluid
Rosenfeld proposed two different scaling approaches to model the transport properties of
fluids, separated by 22 years, one valid in the dilute gas, and another in the liquid phase. In …
fluids, separated by 22 years, one valid in the dilute gas, and another in the liquid phase. In …
Group contribution method for viscosities based on entropy scaling using the perturbed-chain polar statistical associating fluid theory
O Lötgering-Lin, J Gross - Industrial & Engineering Chemistry …, 2015 - ACS Publications
In this work, we propose a new predictive entropy-scaling approach for Newtonian shear
viscosities based on group contributions. The approach is based on Rosenfeld's original …
viscosities based on group contributions. The approach is based on Rosenfeld's original …
Excess-entropy scaling in supercooled binary mixtures
Transport coefficients, such as viscosity or diffusion coefficient, show significant dependence
on density or temperature near the glass transition. Although several theories have been …
on density or temperature near the glass transition. Although several theories have been …
Anomalous phonon scattering and elastic correlations in amorphous solids
A major issue in materials science is why glasses present low-temperature thermal and
vibrational properties that sharply differ from those of crystals. In particular, long-wavelength …
vibrational properties that sharply differ from those of crystals. In particular, long-wavelength …
[HTML][HTML] Revisiting the Stokes-Einstein relation without a hydrodynamic diameter
We present diffusion coefficient and shear viscosity data for the Lennard-Jones fluid along
nine isochores above the critical density, each involving a temperature variation of roughly …
nine isochores above the critical density, each involving a temperature variation of roughly …
Melting Is Well-Known, but Is It Also Well-Understood?
G de With - Chemical Reviews, 2023 - ACS Publications
Contrary to continuous phase transitions, where renormalization group theory provides a
general framework, for discontinuous phase transitions such a framework seems to be …
general framework, for discontinuous phase transitions such a framework seems to be …
Structural order as a genuine control parameter of dynamics in simple glass formers
Glass transition is characterised by drastic dynamical slowing down upon cooling,
accompanied by growing spatial heterogeneity. Its rationalisation by subtle changes in the …
accompanied by growing spatial heterogeneity. Its rationalisation by subtle changes in the …