We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Unrestrained anthropogenic activities have severely disrupted the global natural nitrogen
cycle, causing numerous energy and environmental issues. Electrocatalytic nitrogen …

Electrocatalytic ammonia oxidation (AO) provides an attractive route to a carbon-neutral fuel
economy and the energy-efficient production of value-added feedstocks. The design and …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Molecular catalysts for ammonia oxidation to dinitrogen represent enabling components to
utilize ammonia as a fuel and/or source of hydrogen. Ammonia oxidation requires not only …

Electrocatalytic ammonia oxidation at room temperature and pressure allows energy-
economical and environmentally friendly production of nitrites and nitrates. Few molecular …

In the past few decades, renewable-energy-driven fuel cell technologies have been widely
investigated as promising approaches to alleviate the energy and environmental crisis …

A century after hydrazine was discovered, its synthesis remains a challenge due to its high
energy requirement and favourable subsequent conversion. As an alternative to the …

Ammonia represents one of most promising zero-carbon energy solutions to address the
increasingly urgent climate change problem. However, the existing utilization of ammonia …

Parent amido complexes are crucial intermediates in ammonia-based transformations. We
report a well-defined ferric ammine system [Cp* Fe (1, 2-Ph2PC6H4NH)(NH3)]+([1-NH3]+) …