[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
Molecular catalysts for water oxidation
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …
New avenues for ligand-mediated processes–expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
DLJ Broere, R Plessius, JI van der Vlugt - Chemical Society Reviews, 2015 - pubs.rsc.org
Redox-active ligands have evolved from being considered spectroscopic curiosities–
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …
creating ambiguity about formal oxidation states in metal complexes–to versatile and useful …
Computational electrochemistry: prediction of liquid-phase reduction potentials
This article reviews recent developments and applications in the area of computational
electrochemistry. Our focus is on predicting the reduction potentials of electron transfer and …
electrochemistry. Our focus is on predicting the reduction potentials of electron transfer and …
O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts
XP Zhang, HY Wang, H Zheng, W Zhang… - Chinese Journal of …, 2021 - Elsevier
Water oxidation is one of the most important reactions in natural and artificial energy
conversion schemes. In nature, solar energy is converted to chemical energy via water …
conversion schemes. In nature, solar energy is converted to chemical energy via water …
Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …
experimental results were obtained. With the rapid development of software and hardware …
Redox‐active ligands in catalysis
VKK Praneeth, MR Ringenberg… - Angewandte Chemie …, 2012 - Wiley Online Library
Nature's use of redox‐active moieties combined with 3d transition‐metal ions is a powerful
strategy to promote multi‐electron catalytic reactions. The ability of these moieties to store …
strategy to promote multi‐electron catalytic reactions. The ability of these moieties to store …
Redox-active ligands for chemical, electrochemical, and photochemical molecular conversionsFree GPT-4
A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …
The shrinking world of innocent ligands: conventionaland non‐conventional redox‐active ligands
W Kaim - 2012 - Wiley Online Library
This essay for EurJIC's cluster issue on cooperative and redox non‐innocent ligands
introduces the reader to redox‐active ligands, which range from the small archetypical …
introduces the reader to redox‐active ligands, which range from the small archetypical …
Water oxidation with transition metal catalysts with non-innocent ligands and its mechanisms
Transition metal complexes acting as catalysts towards water oxidation concern a
challenging research topic with high relevance in solar and fuel conversion technologies …
challenging research topic with high relevance in solar and fuel conversion technologies …