Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal …
In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …
provided the basis for assigning coordination number and oxidation state to what were then …
Post-synthetic modifications of metal–organic cages
J Liu, Z Wang, P Cheng, MJ Zaworotko… - Nature Reviews …, 2022 - nature.com
Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …
nodes and organic linkers, which can offer solution processability and high porosity …
Supramolecular transformations within discrete coordination-driven supramolecular architectures
In this review, a comprehensive summary of supramolecular transformations within discrete
coordination-driven supramolecular architectures, including helices, metallacycles …
coordination-driven supramolecular architectures, including helices, metallacycles …
Biomedical and biochemical applications of self-assembled metallacycles and metallacages
Metal ions and metal complexes with organic molecules are ubiquitous in nature. Bulk metal
ions of Na, K, Mg, and Ca constitute as much as 1% of human body weight. The remaining …
ions of Na, K, Mg, and Ca constitute as much as 1% of human body weight. The remaining …
Tailor‐Made PdnL2n Metal‐Organic Cages through Covalent Post‐Synthetic Modification
D Luo, ZJ Yuan, LJ **, XW Zhu, J Zheng… - Angewandte …, 2023 - Wiley Online Library
Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …
Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes
CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …
work in this area has focused on the formation of hollow self-assembled metal-organic …
Construction of multiferrocenyl metallacycles and metallacages via coordination-driven self-assembly: from structure to functions
Recently, the construction of discrete multiferrocenyl organometallic structures via
coordination-driven self-assembly has attracted considerable attention because of their …
coordination-driven self-assembly has attracted considerable attention because of their …
Construction of smart supramolecular polymeric hydrogels cross-linked by discrete organoplatinum (II) metallacycles via post-assembly polymerization
Postassembly modification strategy has been successfully employed in the construction of
discrete metallosupramolecular assemblies. However, the most known reports have been …
discrete metallosupramolecular assemblies. However, the most known reports have been …
Covalent post-assembly modification in metallosupramolecular chemistry
A growing variety of covalent reactions have been employed to achieve the post-assembly
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …
Controlled Formation of Heteroleptic [Pd2(La)2(Lb)2]4+ Cages
Metallosupramolecular architectures are beginning to be exploited for a range of
applications including drug delivery, catalysis, molecular recognition, and sensing. For the …
applications including drug delivery, catalysis, molecular recognition, and sensing. For the …