Equation-of-Motion Coupled-Cluster Cumulant Green's Function for Excited States and X-Ray Spectra

FD Vila, JJ Kas, JJ Rehr, K Kowalski, B Peng - Frontiers in Chemistry, 2021 - frontiersin.org
Green's function methods provide a robust, general framework within many-body theory for
treating electron correlation in both excited states and x-ray spectra. Conventional methods …

Real-Time Equation-of-Motion CCSD Cumulant Green's Function

FD Vila, K Kowalski, B Peng, JJ Kas… - Journal of Chemical …, 2022 - ACS Publications
Many-body excitations in X-ray photoemission spectra have been difficult to simulate from
first principles. We have recently developed a cumulant-based one-electron Green's function …

Accurate prediction of vertical ionization potentials and electron affinities from spin-component scaled CC2 and ADC (2) models

A Shaalan Alag, DP Jelenfi, A Tajti… - Journal of Chemical …, 2022 - ACS Publications
The CC2 and ADC (2) wave function models and their spin-component scaled modifications
are adopted for predicting vertical ionization potentials (VIPs) and electron affinities (VEAs) …

Exploring the statically screened correction to the self-energy: Charged excitations and total energies of finite systems

A Förster, L Visscher - Physical Review B, 2022 - APS
Electron correlation in finite and extended systems is often described in an effective single-
particle framework within the GW approximation. Here, we use the statically screened …

Capturing many-body correlation effects with quantum and classical computing

K Kowalski, NP Bauman, GH Low, M Roetteler, JJ Rehr… - Physical Review A, 2024 - APS
Theoretical descriptions of excited states of molecular systems in high-energy regimes are
crucial for supporting and driving many experimental efforts at light source facilities …

[HTML][HTML] Real-time equation-of-motion CC cumulant and CC Green's function simulations of photoemission spectra of water and water dimer

FD Vila, JJ Rehr, H Pathak, B Peng… - The Journal of …, 2022 - pubs.aip.org
Newly developed coupled-cluster (CC) methods enable simulations of ionization potentials
and spectral functions of molecular systems in a wide range of energy scales ranging from …

[HTML][HTML] Electronic structure simulations in the cloud computing environment

EJ Bylaska, A Panyala, NP Bauman, B Peng… - The Journal of …, 2024 - pubs.aip.org
The transformative impact of modern computational paradigms and technologies, such as
high-performance computing (HPC), quantum computing, and cloud computing, has opened …

Constructing “full-Frequency” spectra via moment constraints for coupled cluster Green's functions

OJ Backhouse, GH Booth - Journal of Chemical Theory and …, 2022 - ACS Publications
We propose an approach to build “full-frequency” quasiparticle spectra from conservation of
a set of static expectation values. These expectation values define the moments of the …

TAMM: Tensor algebra for many-body methods

E Mutlu, A Panyala, N Gawande, A Bagusetty… - The Journal of …, 2023 - pubs.aip.org
Tensor algebra operations such as contractions in computational chemistry consume a
significant fraction of the computing time on largescale computing platforms. The …

Coupled cluster Green's function: Past, present, and future

B Peng, NP Bauman, S Gulania, K Kowalski - Annual reports in …, 2021 - Elsevier
Coupled cluster Green's function (CCGF) approach has drawn much attention in recent
years for targeting the molecular and material electronic structure problems from a many …