Paramagnetic chemical probes for studying biological macromolecules

Q Miao, C Nitsche, H Orton, M Overhand… - Chemical …, 2022 - ACS Publications
Paramagnetic chemical probes have been used in electron paramagnetic resonance (EPR)
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …

Pseudocontact shifts in biomolecular NMR spectroscopy

T Müntener, D Joss, D Häussinger… - Chemical Reviews, 2022 - ACS Publications
Paramagnetic centers in biomolecules, such as specific metal ions that are bound to a
protein, affect the nuclei in their surrounding in various ways. One of these effects is the …

[PDF][PDF] Pseudocontact shifts in biomolecular NMR using paramagnetic metal tags

C Nitsche, G Otting - 2017 - core.ac.uk
Pseudocontact shifts in biomolecular NMR using paramagnetic metal tags Page 1 1
Pseudocontact shifts in biomolecular NMR using paramagnetic metal tags Christoph …

Investigating the structure and function of cupredoxins

C Dennison - Coordination Chemistry Reviews, 2005 - Elsevier
Copper is widely used in nature to promote electron transfer in a variety of processes. The
metal is usually found as a mononuclear type 1 copper site protected by a protein envelope …

Water-Mediated Surface Engineering Enhances High-Voltage Stability of Fast-Charge LiCoO2 Cathodes

X Liu, Y Zhu, L Zhao, S Wang, J Sun, R Xu, Y Sun… - ACS …, 2024 - ACS Publications
Maintaining the surface structure stability of LiCoO2 (LCO) during rapid charge–discharge
processes (> 5C) and under high-voltage conditions (> 4.2 V) is challenging due to …

Spectroscopic and mechanistic studies of heterodimetallic forms of metallo-β-lactamase NDM-1

H Yang, M Aitha, AR Marts, A Hetrick… - Journal of the …, 2014 - ACS Publications
In an effort to characterize the roles of each metal ion in metallo-β-lactamase NDM-1,
heterodimetallic analogues (CoCo-, ZnCo-, and CoCd-) of the enzyme were generated and …

NMR structures of paramagnetic metalloproteins

F Arnesano, L Banci, M Piccioli - Quarterly Reviews of Biophysics, 2005 - cambridge.org
1. Introduction 1681.1 Genomic annotation of metalloproteins 1681.2 Why NMR structures?
1681.3 Why paramagnetic metalloproteins? 1692. General theory 1702.1 Nuclear and …

Paramagnetic resonance of biological metal centers

M Ubbink, JAR Worrall, GW Canters… - Annual review of …, 2002 - annualreviews.org
▪ Abstract The review deals with recent advances in magnetic resonance spectroscopy (hf
EPR and NMR) of paramagnetic metal centers in biological macromolecules. In the first half …

Structural information through NMR hyperfine shifts in blue copper proteins

I Bertini, CO Fernández, BG Karlsson… - Journal of the …, 2000 - ACS Publications
The oxidized blue copper proteins azurin and stellacyanin have been investigated through
1H NMR at 800 MHz and the results compared with those for plastocyanin (Bertini, I.; Ciurli …

Evidence for a dinuclear active site in the metallo-β-lactamase BcII with substoichiometric Co (II): A new model for metal uptake

LI Llarrull, MF Tioni, J Kowalski, B Bennett… - Journal of Biological …, 2007 - jbc.org
Metallo-β-lactamases are zinc-dependent enzymes that constitute one of the main
resistance mechanisms to β-lactam antibiotics. Metallo-β-lactamases have been …