Insights into low thermal conductivity in inorganic materials for thermoelectrics

T Ghosh, M Dutta, D Sarkar… - Journal of the American …, 2022 - ACS Publications
Efficient manipulation of thermal conductivity and fundamental understanding of the
microscopic mechanisms of phonon scattering in crystalline solids are crucial to achieve …

Chemistry in phase change energy storage: Properties regulation on organic phase change materials by covalent bond modification

L Geng, J Cui, C Zhang, Y Yan, J Zhao, C Liu - Chemical Engineering …, 2024 - Elsevier
Phase change materials (PCMs)-based thermal storage systems have a lot of potential uses
in energy storage and temperature control. However, organic PCMs (OPCMs) face …

Glassy thermal conductivity in Cs3Bi2I6Cl3 single crystal

P Acharyya, T Ghosh, K Pal, KS Rana, M Dutta… - Nature …, 2022 - nature.com
As the periodic atomic arrangement of a crystal is made to a disorder or glassy-amorphous
system by destroying the long-range order, lattice thermal conductivity, κL, decreases, and …

Hidden structures: a driving factor to achieve low thermal conductivity and high thermoelectric performance

D Sarkar, A Bhui, I Maria, M Dutta… - Chemical Society Reviews, 2024 - pubs.rsc.org
The long-range periodic atomic arrangement or the lack thereof in solids typically dictates
the magnitude and temperature dependence of their lattice thermal conductivity (κlat) …

Metavalent Bonding-Mediated Dual 6s2 Lone Pair Expression Leads to Intrinsic Lattice Shearing in n-Type TlBiSe2

I Maria, R Arora, M Dutta… - Journal of the …, 2023 - ACS Publications
Metavalent bonding has attracted immense interest owing to its capacity to impart a distinct
property portfolio to materials for advanced functionality. Coupling metavalent bonding to …

Extended antibonding states and phonon localization induce ultralow thermal conductivity in low dimensional metal halide

P Acharyya, K Pal, A Ahad, D Sarkar… - Advanced Functional …, 2023 - Wiley Online Library
Thermal conductivity, which measures the ease at which heat passes through a crystalline
solid, is controlled by the nature of the chemical bonding and periodicity in the solid. This …

All-scale hierarchical nanostructures and superior valence band convergence lead to ultra-high thermoelectric performance in cubic GeTe

D Sarkar, M Samanta, T Ghosh, K Dolui… - Energy & …, 2022 - pubs.rsc.org
GeTe is among the most fascinating inorganic compounds for thermoelectric (TE)
conversion of waste heat into electricity. However, the TE performance in its ambient …

Intrinsically Low Thermal Conductivity in the n-Type Vacancy-Ordered Double Perovskite Cs2SnI6: Octahedral Rotation and Anharmonic Rattling

A Bhui, T Ghosh, K Pal, K Singh Rana… - Chemistry of …, 2022 - ACS Publications
Fundamental understanding of the relationship between chemical bonding, lattice dynamics,
and thermal transport is not only crucial for thermoelectrics but also essential in …

Amorphous‐Like Ultralow Thermal Transport in Crystalline Argyrodite Cu7PS6

X Shen, N Ouyang, Y Huang, YH Tung… - Advanced …, 2024 - Wiley Online Library
Due to their amorphous‐like ultralow lattice thermal conductivity both below and above the
superionic phase transition, crystalline Cu‐and Ag‐based superionic argyrodites have …

Metal halide perovskites as emerging thermoelectric materials

S Hu, Z Ren, AB Djurišić, AL Rogach - ACS Energy Letters, 2021 - ACS Publications
In addition to the broadly anticipated use of metal halide perovskites in photovoltaics and
light-emitting devices, they also hold a great promise as cost-effective thermoelectrics, as …