An overview of synchrotron radiation applications to low temperature geochemistry and environmental science

GE Brown Jr, NC Sturchio - Reviews in Mineralogy and …, 2002 - pubs.geoscienceworld.org
The availability of synchrotron radiation (SR) to the scientific community has literally
revolutionized the way X-ray science is done in many disciplines, including low temperature …

Interpretation of the Changing the Band Gap of Al2O3 Depending on Its Crystalline Form: Connection with Different Local Symmetries

EO Filatova, AS Konashuk - The Journal of Physical Chemistry C, 2015 - ACS Publications
The valence and conduction bands of am-and γ-Al2O3 films grown by the atomic layer
deposition technique were studied simultaneously in identical experimental conditions using …

Structure of aluminum, iron, and other heteroatoms in zeolites by X-ray absorption spectroscopy

JA van Bokhoven, C Lamberti - Coordination Chemistry Reviews, 2014 - Elsevier
Heteroatoms in zeolites provide them their catalytic activity. The silicon atom is always
tetrahedrally coordinated and its valence IV, those of the heteroatoms much more varied …

[HTML][HTML] Al uptake in calcium silicate hydrate and the effect of alkali hydroxide

Y Yan, B Ma, GD Miron, DA Kulik, K Scrivener… - Cement and Concrete …, 2022 - Elsevier
The effect of Al and of pH on the structure of calcium silicate hydrate (CSH), the most
important hydration product in Portland and blended cement, was studied at Ca/Si~ 1.0. The …

Al environment in tectosilicate and peraluminous glasses: A 27Al MQ-MAS NMR, Raman, and XANES investigation

DR Neuville, L Cormier, D Massiot - Geochimica et Cosmochimica Acta, 2004 - Elsevier
Tecto-aluminosilicate and peraluminous glasses have been prepared by conventional and
laser heating techniques, respectively, in the CaO-Al2O3-SiO2 system. The structure of …

Unlocking the secrets of Al-tobermorite in Roman seawater concrete

MD Jackson, SR Chae, SR Mulcahy… - American …, 2013 - pubs.geoscienceworld.org
Abstract Ancient Roman syntheses of Al-tobermorite in a 2000-year-old concrete block
submerged in the Bay of Pozzuoli (Baianus Sinus), near Naples, have unique aluminum-rich …

Three-coordinate aluminum in zeolites observed with in situ X-ray absorption near-edge spectroscopy at the Al K-edge: flexibility of aluminum coordinations in zeolites

JA van Bokhoven, AMJ Van der Eerden… - Journal of the …, 2003 - ACS Publications
Application of in situ X-ray absorption near-edge spectroscopy (XANES) at the Al K-edge
provides unique insight into the flexibilty of the aluminum coordinations in zeolites as a …

Synchrotron X-ray nanotomographic and spectromicroscopic study of the tricalcium aluminate hydration in the presence of gypsum

G Geng, RJ Myers, YS Yu, DA Shapiro… - Cement and Concrete …, 2018 - Elsevier
The rheology of modern Portland cement (PC) concrete critically depends on the correct
dosage of gypsum (calcium sulfate hydrate) to control the hydration of the most reactive …

Micro-and nano-environments of carbon sequestration: Multi-element STXM–NEXAFS spectromicroscopy assessment of microbial carbon and mineral associations

D Solomon, J Lehmann, J Harden, J Wang, J Kinyangi… - Chemical geology, 2012 - Elsevier
Soil represents the largest reservoir of terrestrial organic C, and plays a critical role in global
C cycling. In light of predicted climate change and a more unified approach to mitigate …

XANES spectroscopy of sulfur in earth materials

ME Fleet - The Canadian Mineralogist, 2005 - pubs.geoscienceworld.org
X-ray absorption near-edge structure (XANES) spectroscopy is the ideal non-destructive
technique for characterizing and quantifying S species in compositionally complex natural …