Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Metal–organic frameworks for heterogeneous basic catalysis

L Zhu, XQ Liu, HL Jiang, LB Sun - Chemical reviews, 2017 - ACS Publications
Great attention has been given to metal–organic frameworks (MOFs)-derived solid bases
because of their attractive structure and catalytic performance in various organic reactions …

Asymmetric heterogeneous catalysis

M Heitbaum, F Glorius, I Escher - … Chemie International Edition, 2006 - Wiley Online Library
Limited natural resources and an increasing demand for enantiomerically pure compounds
render catalysis and especially heterogeneous asymmetric catalysis a key technology. The …

Photothermal conversion triggered thermal asymmetric catalysis within metal nanoparticles loaded homochiral covalent organic framework

HC Ma, CC Zhao, GJ Chen, YB Dong - Nature Communications, 2019 - nature.com
For seeking high enantiopurity, the previously reported thermal asymmetric catalysis is
usually carried out at low temperature sometimes with limited yield, that is, the high …

Recyclable stereoselective catalysts

AF Trindade, PMP Gois, CAM Afonso - Chemical reviews, 2009 - ACS Publications
Asymmetric catalysis constitutes one of the most important subjects in chemistry originating
thousands of published works every year. But still, the application of such methodologies in …

Asymmetric Nanocatalysis: N‐Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles

KVS Ranganath, J Kloesges… - Angewandte Chemie …, 2010 - Wiley Online Library
Although asymmetric homogeneous catalysis has been a major focus of academic research
over the past decades, only very few catalytic systems have proven suitable for large-scale …

Synthesis of mesoporous magnesium oxide: Its application to CO2 chemisorption

M Bhagiyalakshmi, JY Lee, HT Jang - International Journal of Greenhouse …, 2010 - Elsevier
Mesoporous magnesium oxide (MgO) was synthesized using mesoporous carbon CMK-3
obtained from mesoporous SBA-15 as exotemplate. P123 was used as the structure …

Recent advances in the catalytic asymmetric nitroaldol (Henry) reaction

C Palomo, M Oiarbide, A Laso - European journal of organic …, 2007 - Wiley Online Library
Catalyst‐controlled enantioselective nitroaldol (or Henry) reactions are presented. These
reactions represent powerful C–C bond‐forming tools and the resulting nitro alcohol …

Magnetically Recyclable Pd Nanoparticles Immobilized on Magnetic Fe3O4@C Nanocomposites: Preparation, Characterization, and Their Catalytic Activity toward …

M Zhu, G Diao - The Journal of Physical Chemistry C, 2011 - ACS Publications
An efficient magnetic carbon nanocomposite supported Pd nanoparticle catalyst has been
prepared by a three-step process in this report. The morphology, inner structure, and …

Diphenylprolinol silyl ether as catalyst of an asymmetric, catalytic, and direct Michael reaction of nitroalkanes with α, β-unsaturated aldehydes

H Gotoh, H Ishikawa, Y Hayashi - Organic letters, 2007 - ACS Publications
A catalytic enantioselective direct conjugate addition of nitroalkanes to α, β-unsaturated
aldehydes using diphenylprolinol silyl ether as an organocatalyst has been developed …