Allenes and computational chemistry: from bonding situations to reaction mechanisms
E Soriano, I Fernández - Chemical Society Reviews, 2014 - pubs.rsc.org
The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …
Noble Metal Porphyrin Complexes. Intermediates of Catalytic Processes (A Review)
EY Tyulyaeva - Russian Journal of Inorganic Chemistry, 2023 - Springer
A wide variety of oxidation states and coordination numbers of complexing cations, various
redox properties, high stability of the coordination center, as well as a unique electronic …
redox properties, high stability of the coordination center, as well as a unique electronic …
Gold (I) and gold (III) corroles
E Rabinovich, I Goldberg… - Chemistry–A European …, 2011 - Wiley Online Library
Corrole complexes with gold (I) and gold (III) were synthesized and their structural,
photophysical, and electrochemical properties investigated. This work includes the X‐ray …
photophysical, and electrochemical properties investigated. This work includes the X‐ray …
Gold (III) compounds for homogeneous catalysis: preparation, reaction conditions, and scope of application
H Schmidbaur, A Schier - Arabian Journal for Science and Engineering, 2012 - Springer
There is currently a rapidly growing interest in the homogeneous catalysis of organic
transformations by gold compounds. In a large number of specific studies, a wide variety of …
transformations by gold compounds. In a large number of specific studies, a wide variety of …
Cycloisomerization of Conjugated Allenones into Furans under Mild Conditions Catalyzed by Ligandless Au Nanoparticles
Au nanoparticles supported on TiO2 (1 mol%) catalyze the quantitative cycloisomerization of
conjugated allenones into furans under very mild conditions. The reaction rate is …
conjugated allenones into furans under very mild conditions. The reaction rate is …
Nucleic acid G-quartets: insights into diverse patterns and optical properties
Structures of various conformers of G-quartets (G4) with different types of hydrogen bonding
patterns have been investigated through various levels of Density Functional Theory (DFT) …
patterns have been investigated through various levels of Density Functional Theory (DFT) …
Phenalenyl in a Different Role: Catalytic Activation through the Nonbonding Molecular Orbital
We have demonstrated that the nonbonding molecular orbital (NBMO) of the phenalenyl
(PLY) cation can be used as a Lewis acid catalyst for different organic transformations …
(PLY) cation can be used as a Lewis acid catalyst for different organic transformations …
Mechanism of Au (III)-mediated alkoxycyclization of a 1, 6-enyne
Gold-mediated homogeneous catalysis is a powerful tool for construction of valuable
molecules and has lately received growing attention. Whereas Au (I)-catalyzed processes …
molecules and has lately received growing attention. Whereas Au (I)-catalyzed processes …
Gold (iii) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?
S Preiß, J Melomedov, AW von Leupoldt… - Chemical Science, 2016 - pubs.rsc.org
Meso tetraarylporphyrinato gold (III) cations bearing different substituents at the aryl
substituents (COOMe, COOH, NO2, NH2, NHAc, H, OnBu, CF3) were prepared and …
substituents (COOMe, COOH, NO2, NH2, NHAc, H, OnBu, CF3) were prepared and …
Theoretical insight into the mechansim and origin of ligand-controlled regioselectivity in homogenous gold-catalyzed intramolecular hydroarylation of alkynes
Y Yang, Y Liu, P Lv, R Zhu, C Liu… - The Journal of Organic …, 2018 - ACS Publications
This work aims at understanding the mechanism and regioselectivity in ligand-controlled
gold-catalyzed divergent intramolecular hydroarylation of alkynes reported by Jiang et al.(J …
gold-catalyzed divergent intramolecular hydroarylation of alkynes reported by Jiang et al.(J …