Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Advances on the merger of electrochemistry and transition metal catalysis for organic synthesis

CA Malapit, MB Prater, JR Cabrera-Pardo, M Li… - Chemical …, 2021 - ACS Publications
Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Pd metal catalysts for cross-couplings and related reactions in the 21st century: a critical review

A Biffis, P Centomo, A Del Zotto, M Zecca - Chemical Reviews, 2018 - ACS Publications
Cross-couplings and related reactions are a class of highly efficient synthetic protocols that
are generally promoted by molecular Pd species as catalysts. However, catalysts based on …

Advances in materials and applications of inorganic electrides

H Hosono, M Kitano - Chemical Reviews, 2021 - ACS Publications
Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …

Coordination engineering in single-site catalysts: General principles, characterizations, and recent advances

H Wang, T Yang, J Wang, Z Zhou, Z Pei, S Zhao - Chem, 2024 - cell.com
Single-site catalysts (SSCs) have long been considered to be promising candidates for
heterogeneous catalysis due to the maximum exposure of metal sites at the catalytic …

A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling

Z Chen, E Vorobyeva, S Mitchell, E Fako… - Nature …, 2018 - nature.com
Palladium-catalysed cross-coupling reactions, central tools in fine-chemical synthesis,
predominantly employ soluble metal complexes despite recognized challenges with product …

Toxicity of metal compounds: knowledge and myths

KS Egorova, VP Ananikov - Organometallics, 2017 - ACS Publications
Organometallic reagents and metal catalysts are used ubiquitously in academia and
industry. Not surprisingly, the biological activity and environmental danger of metal …