Understanding specific ion effects and the Hofmeister series
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
Surface stratification determines the interfacial water structure of simple electrolyte solutions
The distribution of ions at the air/water interface plays a decisive role in many natural
processes. Several studies have reported that larger ions tend to be surface-active, implying …
processes. Several studies have reported that larger ions tend to be surface-active, implying …
Electrolytes at uncharged liquid interfaces: Adsorption, potentials, surface tension, and the role of the surfactant monolayer
RI Slavchov, B Peychev, I Minkov - Langmuir, 2024 - ACS Publications
The article summarizes the results of our research on the behavior of ions at uncharged fluid
interfaces, with a focus on moderately to highly concentrated aqueous electrolytes. The ion …
interfaces, with a focus on moderately to highly concentrated aqueous electrolytes. The ion …
Nature of cations critically affects water at the negatively charged silica interface
Understanding the collective behavior of ions at charged surfaces is of paramount
importance for geological and electrochemical processes. Ions screen the surface charge …
importance for geological and electrochemical processes. Ions screen the surface charge …
Room temperature bilayer water structures on a rutile TiO 2 (110) surface: hydrophobic or hydrophilic?
M Qu, G Huang, X Liu, X Nie, C Qi, H Wang, J Hu… - Chemical …, 2022 - pubs.rsc.org
The lack of understanding of the molecular-scale water adsorbed on TiO2 surfaces under
ambient conditions has become a major obstacle for solving the long-time scientific and …
ambient conditions has become a major obstacle for solving the long-time scientific and …
Second-order vibrational lineshapes from the air/water interface
We explore by means of modeling how absorptive–dispersive mixing between the second-
and third-order terms modifies the imaginary χtotal (2) responses from air/water interfaces …
and third-order terms modifies the imaginary χtotal (2) responses from air/water interfaces …
Salt solutions in carbon nanotubes: the role of cation− π interactions
Understanding the structure of aqueous electrolytes at interfaces is essential for predicting
and optimizing device performance for a wide variety of emerging energy and environmental …
and optimizing device performance for a wide variety of emerging energy and environmental …
Specifics about specific ion adsorption from heterodyne-detected second harmonic generation
Ion specific outcomes at aqueous interfaces remain among the most enigmatic phenomena
in interfacial chemistry. Here, charged fused silica/water interfaces have been probed by …
in interfacial chemistry. Here, charged fused silica/water interfaces have been probed by …
Theoretical Study of the Two-Dimensional Vibrational Sum Frequency Generation Spectroscopy of the Air–Water Interface at Varying Temperature and Its …
We performed a theoretical study of the temperature variation of two-dimensional vibrational
sum frequency generation (2D-VSFG) spectra of the OH stretch modes at air–water …
sum frequency generation (2D-VSFG) spectra of the OH stretch modes at air–water …
Direct Observation of Carbon Dioxide Electroreduction on Gold: Site Blocking by the Stern Layer Controls CO2 Adsorption Kinetics
S Wallentine, S Bandaranayake… - The Journal of …, 2020 - ACS Publications
Directly observing active surface intermediates represents a major challenge in
electrocatalysis, especially for CO2 electroreduction on Au. We use in-situ, plasmon …
electrocatalysis, especially for CO2 electroreduction on Au. We use in-situ, plasmon …