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Umbellate distortions of the uranyl coordination environment result in a stable and porous polycatenated framework that can effectively remove cesium from aqueous …
Searching for new chemically durable and radiation-resistant absorbent materials for
actinides and their fission products generated in the nuclear fuel cycle remain highly …
actinides and their fission products generated in the nuclear fuel cycle remain highly …
Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides
This frontier article focuses on the use of flux crystal growth for the preparation of new
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
The layered uranyl silicate mineral uranophane-β: Crystal structure, mechanical properties, Raman spectrum and comparison with the α-polymorph
F Colmenero, J Plášil, J Sejkora - Dalton Transactions, 2019 - pubs.rsc.org
The crystal structure, elastic properties and the Raman spectrum of the layered calcium
uranyl silicate pentahydrate mineral uranophane-β, Ca (UO2) 2Si2O6 (OH) 2· 5H2O, are …
uranyl silicate pentahydrate mineral uranophane-β, Ca (UO2) 2Si2O6 (OH) 2· 5H2O, are …
[UO2Cl2(phen)2], a Simple Uranium(VI) Compound with a Significantly Bent Uranyl Unit (phen=1,10‐phenanthroline)
S Schöne, T Radoske, J März, T Stumpf… - … A European Journal, 2017 - Wiley Online Library
A simple synthesis based on UO2Cl2⋅ n H2O and 1, 10‐phenanthroline (phen) resulted in
the formation of a new uranyl (VI) complex [UO2Cl2 (phen) 2](1), revealing a unique …
the formation of a new uranyl (VI) complex [UO2Cl2 (phen) 2](1), revealing a unique …
Observation of an Unusual Uranyl Cation–Cation Interaction in the Strongly Fluorescent Layered Uranyl Phosphates Rb6[(UO2)7O4(PO4)4] and Cs6[(UO2)7O4(PO4) …
Single crystals of two new uranyl phosphates, A6 [(UO2) 7O4 (PO4) 4](A= Cs, Rb), featuring
cation–cation interactions (CCIs) rarely observed in uranium (VI) compounds were …
cation–cation interactions (CCIs) rarely observed in uranium (VI) compounds were …
A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2 …
Single crystals of eight new layered uranyl phosphates were grown from alkali chloride
fluxes: Cs1. 4K2. 6 [(UO2) 3O2 (PO4) 2], Cs0. 7K3. 3 [(UO2) 3O2 (PO4) 2], Rb1. 4K2. 6 …
fluxes: Cs1. 4K2. 6 [(UO2) 3O2 (PO4) 2], Cs0. 7K3. 3 [(UO2) 3O2 (PO4) 2], Rb1. 4K2. 6 …
Application of a mild hydrothermal method to the synthesis of mixed transition-metal (II)/uranium (IV) fluorides
J Felder, J Yeon, M Smith, HC zur Loye - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
Single crystals of five transition metal uranium fluorides were obtained via the use of a mild
hydrothermal route. Uranyl acetate was used as both the uranium source and the reducing …
hydrothermal route. Uranyl acetate was used as both the uranium source and the reducing …
Structural and thermophysical properties of Sr7U (PO4) 6 and Ba7U (PO4) 6
Abstract Compounds Sr 7 U (PO 4) 6 (1) and Ba 7 U (PO 4) 6 (2) were prepared by the solid
state reaction route, by mixing appropriate molar proportions of alkaline earth metal …
state reaction route, by mixing appropriate molar proportions of alkaline earth metal …
Achieving and Stabilizing Uranyl Bending via Physical Pressure
Applying physical pressure in the uranyl–sulfate system has resulted in the formation of the
first purely inorganic uranyl oxo-salt phase with a considerable uranyl bend: Na4 …
first purely inorganic uranyl oxo-salt phase with a considerable uranyl bend: Na4 …
Crystal growth and structure characterization of three layered uranyl phosphates and their relation to the phosphuranylite family
CA Juillerat, HC zur Loye - Crystal Growth & Design, 2018 - ACS Publications
Three new materials related to the phosphuranylite family were synthesized by using alkali
chloride fluxes at 875° C: CsNa3 [(UO2) 3O2 (PO4) 2](1), Cs2Na4 [(UO2) 5O5 (PO4) 2](2) …
chloride fluxes at 875° C: CsNa3 [(UO2) 3O2 (PO4) 2](1), Cs2Na4 [(UO2) 5O5 (PO4) 2](2) …