Multi‐photon excitation in photoredox catalysis: concepts, applications, methods

F Glaser, C Kerzig, OS Wenger - … Chemie International Edition, 2020 - Wiley Online Library
The energy of visible photons and the accessible redox potentials of common photocatalysts
set thermodynamic limits to photochemical reactions that can be driven by traditional visible …

Recent progress in the development of transition-metal based photoredox catalysts

F Glaser, OS Wenger - Coordination chemistry reviews, 2020 - Elsevier
Photoredox catalysis is an old concept that has experienced a remarkable revival in the past
decade, leading to important progress in organic synthesis. Many of the current photoredox …

Asymmetric photoredox catalytic formal de Mayo reaction enabled by sensitization-initiated electron transfer

X Sun, Y Liu, Y Yin, X Ban, X Zhao, Z Jiang - Nature Chemistry, 2024 - nature.com
Visible-light-driven photoredox catalysis is known to be a powerful tool for organic synthesis.
Its occurrence critically depends on the twice exothermic single-electron transfer processes …

Two-photon-absorbing ruthenium complexes enable near infrared light-driven photocatalysis

G Han, G Li, J Huang, C Han, C Turro, Y Sun - Nature Communications, 2022 - nature.com
One-photon-absorbing photosensitizers are commonly used in homogeneous
photocatalysis which require the absorption of ultraviolet (UV)/visible light to populate the …

Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis

F Glaser, OS Wenger - JACS Au, 2022 - ACS Publications
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …

Photocatalytic strategies for the activation of organic chlorides

M Cybularczyk-Cecotka, J Szczepanik, M Giedyk - Nature Catalysis, 2020 - nature.com
Driven by the continuous demand for sustainable organic synthesis, the field of
photocatalysis has emerged as a powerful manifold for direct modification of various …

Sensitization‐Initiated Electron Transfer for Photoredox Catalysis

I Ghosh, RS Shaikh, B König - … Chemie International Edition, 2017 - Wiley Online Library
Photosynthetic organisms exploit antenna chromophores to absorb light and transfer
excitation energy to the reaction center where redox reactions occur. In contrast, in visible …

Sensitizer-controlled photochemical reactivity via upconversion of red light

F Glaser, OS Wenger - Chemical Science, 2023 - pubs.rsc.org
By combining the energy input from two red photons, chemical reactions that would normally
require blue or ultraviolet irradiation become accessible. Key advantages of this biphotonic …

Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop

SB Beil, S Bonnet, C Casadevall, RJ Detz… - JACS Au, 2024 - ACS Publications
Photocatalysis is a versatile and rapidly develo** field with applications spanning artificial
photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular …

Photocatalytic activation of alkyl chlorides by assembly-promoted single electron transfer in microheterogeneous solutions

M Giedyk, R Narobe, S Weiß, D Touraud, W Kunz… - Nature Catalysis, 2020 - nature.com
Photoredox catalysis has developed into a powerful tool for the synthesis of organic
compounds with diverse structures. However, stable carbon–chloride bonds remain beyond …