Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

J‐aggregates: from serendipitous discovery to supramolecular engineering of functional dye materials

F Würthner, TE Kaiser… - Angewandte Chemie …, 2011 - Wiley Online Library
J‐aggregates are of significant interest for organic materials conceived by supramolecular
approaches. Their discovery in the 1930s represents one of the most important milestones in …

Enhanced two‐photon absorption of organic chromophores: theoretical and experimental assessments

F Terenziani, C Katan, E Badaeva, S Tretiak… - Advanced …, 2008 - Wiley Online Library
Functional organic materials with enhanced two‐photon absorption lead to new
technologies in the fields of chemistry, biology, and photonics. In this article we review …

Fluorescent J-aggregates of core-substituted perylene bisimides: studies on structure− property relationship, nucleation− elongation mechanism, and sergeants-and …

TE Kaiser, V Stepanenko… - Journal of the American …, 2009 - ACS Publications
A series of highly soluble and fluorescent, at core tetraaryloxy-substituted and in imide
positions hydrogen atom containing perylene bisimide (PBI) dyes 1a− e with varying …

Dynamic disorder dominates delocalization, transport, and recombination in halide perovskites

KT Munson, ER Kennehan, GS Doucette, JB Asbury - Chem, 2018 - cell.com
We investigate the origins of exceptionally long charge-carrier lifetimes of halide perovskites
by using temperature-dependent and time-resolved mid-infrared spectroscopy. We report …

Photonics meets excitonics: natural and artificial molecular aggregates

SK Saikin, A Eisfeld, S Valleau, A Aspuru-Guzik - Nanophotonics, 2013 - degruyter.com
Organic molecules store the energy of absorbed light in the form of charge-neutral molecular
excitations–Frenkel excitons. Usually, in amorphous organic materials, excitons are viewed …

Excitons in conjugated oligomer aggregates, films, and crystals

FC Spano - Annu. Rev. Phys. Chem., 2006 - annualreviews.org
▪ Abstract Recent experimental and theoretical investigations of excitons in conjugated
oligomer nanoaggregates, thin films, and crystals are reviewed. The review focuses on the …

Determining exciton coherence from the photoluminescence spectral line shape in poly (3-hexylthiophene) thin films

FC Spano, J Clark, C Silva, RH Friend - The Journal of chemical …, 2009 - pubs.aip.org
The photoluminescence (PL) spectral line shape of regioregular poly (3-hexylthiophene)
thin films is analyzed using a model which treats the polymer π-stacks as H-aggregates with …

Vibronic coupling in J-aggregates and beyond: a direct means of determining the exciton coherence length from the photoluminescence spectrum

FC Spano, H Yamagata - The Journal of Physical Chemistry B, 2011 - ACS Publications
Exciton coherence in a J-aggregate with exciton− phonon coupling involving a single
intramolecular vibration is studied. For linear aggregates with no disorder and periodic …

Self-trap** of excitons, violation of Condon approximation, and efficient fluorescence in conjugated cycloparaphenylenes

L Adamska, I Nayyar, H Chen, AK Swan, N Oldani… - Nano …, 2014 - ACS Publications
Cycloparaphenylenes, the simplest structural unit of armchair carbon nanotubes, have
unique optoelectronic properties counterintuitive in the class of conjugated organic …